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Multi-Functional Ethylene-vinyl Acetate Copolymer Flexible Composite Film Embedded with Indium Acetate-Passivated Perovskite Quantum Dots

In recent years, all-inorganic cesium lead halide perovskite quantum dots have emerged as promising candidates for various optoelectronic applications, including sensors, light-emitting diodes, and solar cells, owing to their exceptional photoelectric properties. However, their commercial utilizatio...

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Autores principales: Huang, Sheng, Gao, Shasha, Zhang, Hui, Bian, Ce, Zhao, Yulong, Gu, Xiuquan, Xu, Wenjie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10575095/
https://www.ncbi.nlm.nih.gov/pubmed/37836035
http://dx.doi.org/10.3390/polym15193986
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author Huang, Sheng
Gao, Shasha
Zhang, Hui
Bian, Ce
Zhao, Yulong
Gu, Xiuquan
Xu, Wenjie
author_facet Huang, Sheng
Gao, Shasha
Zhang, Hui
Bian, Ce
Zhao, Yulong
Gu, Xiuquan
Xu, Wenjie
author_sort Huang, Sheng
collection PubMed
description In recent years, all-inorganic cesium lead halide perovskite quantum dots have emerged as promising candidates for various optoelectronic applications, including sensors, light-emitting diodes, and solar cells, owing to their exceptional photoelectric properties. However, their commercial utilization has been limited by stability issues. In this study, we addressed this challenge by passivating the surface defects of CsPbBr(3) quantum dots using indium acetate, a metal–organic compound. The resulting CsPbBr(3) quantum dots exhibited not only high photoluminescence intensity, but also a remarkably narrow half-peak width of 19 nm. Furthermore, by embedding the CsPbBr(3) quantum dots in ethylene-vinyl acetate, we achieved stretchability and significantly enhanced stability while preserving the original luminous intensity. The resulting composite film demonstrated the potential to improve the power conversion efficiency of crystalline silicon solar cells and enabled the creation of excellent white light-emitting diodes with coordinates of (0.33, 0.31). This co-passivation strategy, involving surface passivation and polymer packaging, provides a new idea for the practical application of CsPbBr(3) quantum dots.
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spelling pubmed-105750952023-10-14 Multi-Functional Ethylene-vinyl Acetate Copolymer Flexible Composite Film Embedded with Indium Acetate-Passivated Perovskite Quantum Dots Huang, Sheng Gao, Shasha Zhang, Hui Bian, Ce Zhao, Yulong Gu, Xiuquan Xu, Wenjie Polymers (Basel) Article In recent years, all-inorganic cesium lead halide perovskite quantum dots have emerged as promising candidates for various optoelectronic applications, including sensors, light-emitting diodes, and solar cells, owing to their exceptional photoelectric properties. However, their commercial utilization has been limited by stability issues. In this study, we addressed this challenge by passivating the surface defects of CsPbBr(3) quantum dots using indium acetate, a metal–organic compound. The resulting CsPbBr(3) quantum dots exhibited not only high photoluminescence intensity, but also a remarkably narrow half-peak width of 19 nm. Furthermore, by embedding the CsPbBr(3) quantum dots in ethylene-vinyl acetate, we achieved stretchability and significantly enhanced stability while preserving the original luminous intensity. The resulting composite film demonstrated the potential to improve the power conversion efficiency of crystalline silicon solar cells and enabled the creation of excellent white light-emitting diodes with coordinates of (0.33, 0.31). This co-passivation strategy, involving surface passivation and polymer packaging, provides a new idea for the practical application of CsPbBr(3) quantum dots. MDPI 2023-10-04 /pmc/articles/PMC10575095/ /pubmed/37836035 http://dx.doi.org/10.3390/polym15193986 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Huang, Sheng
Gao, Shasha
Zhang, Hui
Bian, Ce
Zhao, Yulong
Gu, Xiuquan
Xu, Wenjie
Multi-Functional Ethylene-vinyl Acetate Copolymer Flexible Composite Film Embedded with Indium Acetate-Passivated Perovskite Quantum Dots
title Multi-Functional Ethylene-vinyl Acetate Copolymer Flexible Composite Film Embedded with Indium Acetate-Passivated Perovskite Quantum Dots
title_full Multi-Functional Ethylene-vinyl Acetate Copolymer Flexible Composite Film Embedded with Indium Acetate-Passivated Perovskite Quantum Dots
title_fullStr Multi-Functional Ethylene-vinyl Acetate Copolymer Flexible Composite Film Embedded with Indium Acetate-Passivated Perovskite Quantum Dots
title_full_unstemmed Multi-Functional Ethylene-vinyl Acetate Copolymer Flexible Composite Film Embedded with Indium Acetate-Passivated Perovskite Quantum Dots
title_short Multi-Functional Ethylene-vinyl Acetate Copolymer Flexible Composite Film Embedded with Indium Acetate-Passivated Perovskite Quantum Dots
title_sort multi-functional ethylene-vinyl acetate copolymer flexible composite film embedded with indium acetate-passivated perovskite quantum dots
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10575095/
https://www.ncbi.nlm.nih.gov/pubmed/37836035
http://dx.doi.org/10.3390/polym15193986
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