Built-In Electric Field-Driven Ultrahigh-Rate K-Ion Storage via Heterostructure Engineering of Dual Tellurides Integrated with Ti(3)C(2)T(x) MXene

Exploiting high-rate anode materials with fast K(+) diffusion is intriguing for the development of advanced potassium-ion batteries (KIBs) but remains unrealized. Here, heterostructure engineering is proposed to construct the dual transition metal tellurides (CoTe(2)/ZnTe), which are anchored onto two-dimensional (2D) Ti(3)C(2)T(x) MXene nanosheets. Various theoretical modeling and experimental findings reveal that heterostructure engineering can regulate the electronic structures of CoTe(2)/ZnTe interfaces, improving K(+) diffusion and adsorption. In addition, the different work functions between CoTe(2)/ZnTe induce a robust built-in electric field at the CoTe(2)/ZnTe interface, providing a strong driving force to facilitate charge transport. Moreover, the conductive and elastic Ti(3)C(2)T(x) can effectively promote electrode conductivity and alleviate the volume change of CoTe(2)/ZnTe heterostructures upon cycling. Owing to these merits, the resulting CoTe(2)/ZnTe/Ti(3)C(2)T(x) (CZT) exhibit excellent rate capability (137.0 mAh g(−1) at 10 A g(−1)) and cycling stability (175.3 mAh g(−1) after 4000 cycles at 3.0 A g(−1), with a high capacity retention of 89.4%). More impressively, the CZT-based full cells demonstrate high energy density (220.2 Wh kg(−1)) and power density (837.2 W kg(−1)). This work provides a general and effective strategy by integrating heterostructure engineering and 2D material nanocompositing for designing advanced high-rate anode materials for next-generation KIBs. [Image: see text] SUPPLEMENTARY INFORMATION: The online version contains supplementary material available at 10.1007/s40820-023-01202-6.