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Polaritonic Chemistry: Hindering and Easing Ground State Polyenic Isomerization via Breakdown of σ–π Separation
[Image: see text] The ground state conformational isomerization in polyenes is a symmetry allowed process. Its low energy barrier is governed by electron density transfer from the formal single bond that is rotated to the nearby formal double bonds. Along the reaction pathway, the transition state i...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10577679/ https://www.ncbi.nlm.nih.gov/pubmed/37796008 http://dx.doi.org/10.1021/acs.jpclett.3c02081 |