A-Band Absorption Spectrum of the ClSO Radical: Electronic Structure of the Sulfinyl Group

[Image: see text] Sulfur oxide species (RSO(x)) play a critical role in many fields, ranging from biology to atmospheric chemistry. Chlorine-containing sulfur oxides may play a key role in sulfate aerosol formation in Venus’ cloud layer by catalyzing the oxidation of SO to SO(2) via sulfinyl radicals (RSO). We present results from the gas-phase UV–vis transient absorption spectroscopy study of the simplest sulfinyl radical, ClSO, generated from the pulsed-laser photolysis of thionyl chloride at 248 nm (at 40 Torr of N(2) and 292 K). A weak absorption spectrum from 350 to 480 nm with a peak at 385 nm was observed, with partially resolved vibronic bands (spacing = 226 cm(–1)), and a peak cross section σ(385 nm) = (7.6 ± 1.9) × 10(–20) cm(2). From ab initio calculations at the EOMEE-CCSD/ano-pVQZ level, we assigned this band to 1(2)A′ ← X(2)A″ and 2(2)A′ ← X(2)A″ transitions. The spectrum was modeled as a sum of a bound-to-free transition to the 1(2)A′ state and a bound-to-bound transition to the 2(2)A′ state with similar oscillator strengths; the prediction agreed well with the observed spectrum. We attributed the vibronic structure to a progression in the bending vibration of the 2(2)A′ state. Further calculations at the XDW-CASPT2 level predicted a conical intersection between the excited 1(2)A′ and 2(2)A′ potential energy surfaces near the Franck–Condon region. The geometry of the minimum-energy conical intersection was similar to that of the ground-state geometry. The lack of structure at shorter wavelengths could be evidence of a short excited-state lifetime arising from strong vibronic coupling. From simplified molecular orbital analysis, we attributed the ClSO spectrum to transitions involving the out-of-plane π/π(*) orbitals along the S–O bond and the in-plane orbital possessing a σ/σ(*) character along the S–Cl bond. We hypothesize that these orbitals are common to other sulfinyl radicals, RSO, which would share a combination of a strong and a weak transition in the UV (near 300 nm) and visible (400–600 nm) regions.