Singlet and Triplet Pathways Determine the Thermal Z/E Isomerization of an Arylazopyrazole-Based Photoswitch

[Image: see text] Understanding the thermal isomerization mechanism of azobenzene derivatives is essential to designing photoswitches with tunable half-lives. Herein, we employ quantum chemical calculations, nonadiabatic transition state theory, and photosensitized experiments to unravel the thermal...

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Detalles Bibliográficos
Autores principales: Singer, Nadja K., Schlögl, Katharina, Zobel, J. Patrick, Mihovilovic, Marko D., González, Leticia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10577781/
https://www.ncbi.nlm.nih.gov/pubmed/37772734
http://dx.doi.org/10.1021/acs.jpclett.3c01785

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10577781/
https://www.ncbi.nlm.nih.gov/pubmed/37772734
http://dx.doi.org/10.1021/acs.jpclett.3c01785

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