Cargando…

Singlet and Triplet Pathways Determine the Thermal Z/E Isomerization of an Arylazopyrazole-Based Photoswitch

[Image: see text] Understanding the thermal isomerization mechanism of azobenzene derivatives is essential to designing photoswitches with tunable half-lives. Herein, we employ quantum chemical calculations, nonadiabatic transition state theory, and photosensitized experiments to unravel the thermal...

Descripción completa

Detalles Bibliográficos
Autores principales:	Singer, Nadja K., Schlögl, Katharina, Zobel, J. Patrick, Mihovilovic, Marko D., González, Leticia
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2023
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10577781/ https://www.ncbi.nlm.nih.gov/pubmed/37772734 http://dx.doi.org/10.1021/acs.jpclett.3c01785

Ejemplares similares

Photoisomerization of Arylazopyrazole Photoswitches: Stereospecific Excited‐State Relaxation
por: Wang, Ya‐Ting, et al.
Publicado: (2016)

pH Tuning of Water‐Soluble Arylazopyrazole Photoswitches
por: Ludwanowski, Simon, et al.
Publicado: (2020)

Biological Properties of Heparins Modified with an Arylazopyrazole-Based Photoswitch
por: Stolarek, Marta, et al.
Publicado: (2023)

Systematic Investigation into the Photoswitching and Thermal Properties of Arylazopyrazole-based MOF Host–Guest Complexes
por: Griffiths, Kieran, et al.
Publicado: (2023)

Far-red triplet sensitized Z-to-E photoswitching of azobenzene in bioplastics
por: Bharmoria, Pankaj, et al.
Publicado: (2022)

Light-mediated multi-target protein degradation using arylazopyrazole photoswitchable PROTACs (AP-PROTACs)
por: Zhang, Qisi, et al.
Publicado: (2022)

Branching mechanism of photoswitching in an Fe(II) polypyridyl complex explained by full singlet-triplet-quintet dynamics
por: Rozgonyi, Tamás, et al.
Publicado: (2023)

Singlet Triplet-Pair Production and Possible Singlet-Fission in Carotenoids
por: Manawadu, Dilhan, et al.
Publicado: (2022)

Ultrafast and long-time excited state kinetics of an NIR-emissive vanadium(iii) complex II. Elucidating triplet-to-singlet excited-state dynamics
por: Zobel, J. Patrick, et al.
Publicado: (2021)

Selection of isomerization pathways of multistep photoswitches by chalcogen bonding
por: Jia, Shuaipeng, et al.
Publicado: (2023)

Thermally Stable Photomechanical Molecular Hinge: Sterically Hindered Stiff-Stilbene Photoswitch Mechanically Isomerizes
por: Imato, Keiichi, et al.
Publicado: (2023)

Thermally controlling the singlet–triplet energy gap of a diradical in the solid state
por: Su, Yuanting, et al.
Publicado: (2016)

Method for accurate experimental determination of singlet and triplet exciton diffusion between thermally activated delayed fluorescence molecules
por: Jakoby, Marius, et al.
Publicado: (2020)

Reactions of carbanions with triplet and singlet molecular oxygen.
por: Bierbaum, V M, et al.
Publicado: (1980)

Organic molecules with inverted singlet-triplet gaps
por: Li, Jie, et al.
Publicado: (2022)

Simultaneous Singlet–Singlet and Triplet–Singlet Förster Resonance Energy Transfer from a Single Donor Material
por: Kirch, Anton, et al.
Publicado: (2019)

Thermal equilibration between singlet and triplet excited states in organic fluorophore for submicrosecond delayed fluorescence
por: Aizawa, Naoya, et al.
Publicado: (2021)

Numerical study of the singlet-triplet model for cuprate superconductors
por: Simón, M E, et al.
Publicado: (1994)

Singlet-doublet/triplet dark matter and neutrino masses
por: Fiaschi, Juri, et al.
Publicado: (2019)

Noise filtering of composite pulses for singlet-triplet qubits
por: Yang, Xu-Chen, et al.
Publicado: (2016)

The inverted singlet–triplet gap: a vanishing myth?
por: Dreuw, Andreas, et al.
Publicado: (2023)

Trace mild acid-catalysed Z → E isomerization of norbornene-fused stilbene derivatives: intelligent chiral molecular photoswitches with controllable self-recovery
por: Hao, Taotao, et al.
Publicado: (2020)

Genetic Encoding of Arylazopyrazole Phenylalanine for Optical Control of Translation
por: Janosko, Chasity P., et al.
Publicado: (2023)

Photoswitchable and long-lived seven-membered cyclic singlet diradicals for the bioorthogonal photoclick reaction
por: Hu, Fuqiang, et al.
Publicado: (2023)

Distinct properties of the triplet pair state from singlet fission
por: Trinh, M. Tuan, et al.
Publicado: (2017)

Multiplicity conversion based on intramolecular triplet-to-singlet energy transfer
por: Cravcenco, A., et al.
Publicado: (2019)

Parallel triplet formation pathways in a singlet fission material
por: Maity, Nilabja, et al.
Publicado: (2022)

Delayed fluorescence from inverted singlet and triplet excited states
por: Aizawa, Naoya, et al.
Publicado: (2022)

Photoswitchable molecular tweezers: isomerization to control substrate binding, and what about vice versa?
por: Wezenberg, Sander J.
Publicado: (2022)

Reversible switching of arylazopyrazole within a metal–organic cage
por: Hanopolskyi, Anton I, et al.
Publicado: (2019)

Opposite Anisotropy Effects of Singlet and Triplet Exciton Diffusion in Tetracene Crystal
por: Xie, Xiaoyu, et al.
Publicado: (2016)

A silicon singlet–triplet qubit driven by spin-valley coupling
por: Jock, Ryan M., et al.
Publicado: (2022)

Soluble Diphenylhexatriene Dimers for Intramolecular Singlet Fission with High Triplet Energy
por: Millington, Oliver, et al.
Publicado: (2023)

Multiphoton excited singlet/triplet mixed self-trapped exciton emission
por: Zhou, Rui, et al.
Publicado: (2023)

Promoting multiexciton interactions in singlet fission and triplet fusion upconversion dendrimers
por: He, Guiying, et al.
Publicado: (2023)

Direct population of triplet excited states through singlet–triplet transition for visible-light excitable organic afterglow
por: Yuan, Jie, et al.
Publicado: (2019)

Solid cyclooctatetraene-based triplet quencher demonstrating excellent suppression of singlet–triplet annihilation in optical and electrical excitation
por: Mai, Van T. N., et al.
Publicado: (2020)

Thermal and Mechanochemical Tuning of the Porphyrin Singlet-Triplet Gap for Selective Energy Transfer Processes: A Molecular Dynamics Approach
por: Zapata, Felipe, et al.
Publicado: (2021)

Highly efficient blue thermally activated delayed fluorescent OLEDs with record-low driving voltages utilizing high triplet energy hosts with small singlet–triplet splittings
por: Zhang, Dongdong, et al.
Publicado: (2016)

Photocatalytic Isomerization of (E)-Anethole to (Z)-Anethole
por: Korff, Marvin, et al.
Publicado: (2022)

Cannot write session to /tmp/vufind_sessions/sess_se3r0di250q916jumm0nn4k85m