Mechanism Study of Stress Corrosion Behavior under Tensile and Compressive Stresses for Welded Joint Used in Nuclear Turbine Rotor

Stress corrosion damage containing pitting and cracking was investigated for NiCrMoV steel-welded joint used in nuclear turbine rotor in 3.5% NaCl solution. The U-bend specimen containing tensile face and compressive face was adopted which was conducive to study the effects of stress on pitting and stress corrosion cracking. On tensile surface of U-bend specimen, pit grew in open environment and was converted into crack covered with passivated film. Interestingly, corrosion pit was also found on compressive surface, which might attribute to this location creating enclosed environment causing Cl(−) to diffuse hardly. Then, pit grew under the occluded oxide crust composed of special crystalline corrosion products. When pit approached to critical size, crack initiated from it. The critical size of pit for crack initiation from pit was 35 μm on tensile surface and 95 μm on compressive surface. The sensitivity of crack initiation in tensile surface was higher than that in compressive surface. Then, cracking on compressive surface was controlled by slip dissolution mechanism, that is, dislocation outcrop generated through plastic deformation during manufacturing and absorbed Cl(−) in enclosed environment to accelerate metal dissolution and film rupture. Thereupon, the stress corrosion cracking on compressive surface was able to be maintained. The findings compared corrosion damage modes caused by the two kinds of stress and emphasized the nonignorable role of compressive stress on stress corrosion damage.