Stepwise conversion of the Cys(6)[4Fe–3S] to a Cys(4)[4Fe–4S] cluster and its impact on the oxygen tolerance of [NiFe]-hydrogenase

The membrane-bound [NiFe]-hydrogenase of Cupriavidus necator is a rare example of a truly O(2)-tolerant hydrogenase. It catalyzes the oxidation of H(2) into 2e(−) and 2H(+) in the presence of high O(2) concentrations. This characteristic trait is intimately linked to the unique Cys(6)[4Fe–3S] cluste...

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Detalles Bibliográficos
Autores principales: Schmidt, Andrea, Kalms, Jacqueline, Lorent, Christian, Katz, Sagie, Frielingsdorf, Stefan, Evans, Rhiannon M., Fritsch, Johannes, Siebert, Elisabeth, Teutloff, Christian, Armstrong, Fraser A., Zebger, Ingo, Lenz, Oliver, Scheerer, Patrick
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10583674/
https://www.ncbi.nlm.nih.gov/pubmed/37860641
http://dx.doi.org/10.1039/d3sc03739h

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