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Reversible C–H bond silylation with a neutral silicon Lewis acid

The silicon–carbon bond is a valuable linchpin for synthetic transformations. However, installing Si–C functionalities requires metalated C-nucleophiles, activated silicon reagents (silylium ions, silyl radicals, and silyl anions), or transition metal catalysis, and it occurs irreversibly. In contra...

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Detalles Bibliográficos
Autores principales: Thorwart, Thaddäus, Greb, Lutz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10583699/
https://www.ncbi.nlm.nih.gov/pubmed/37860638
http://dx.doi.org/10.1039/d3sc03488g