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Reversible C–H bond silylation with a neutral silicon Lewis acid
The silicon–carbon bond is a valuable linchpin for synthetic transformations. However, installing Si–C functionalities requires metalated C-nucleophiles, activated silicon reagents (silylium ions, silyl radicals, and silyl anions), or transition metal catalysis, and it occurs irreversibly. In contra...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10583699/ https://www.ncbi.nlm.nih.gov/pubmed/37860638 http://dx.doi.org/10.1039/d3sc03488g |