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Exploiting the (–C–H···C–) Interaction to Design Cage-Functionalized Organic Superbases and Hyperbases: A Computational Study
[Image: see text] A set of carbon center-based P-ylidesubstituting bases have been exploited computationally with pentacyclo[5.4.0.0(2,6).0(3,10).0(5.9)]undecane (PCU) and pentacyclo [6.4.0.0(2,7).0(3,11).0(6,10)] dodecane (PCD) scaffolds using the B3LYP-D3/6-311+G(d,p) level of theory. The proton a...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10586256/ https://www.ncbi.nlm.nih.gov/pubmed/37867725 http://dx.doi.org/10.1021/acsomega.3c05401 |