Metal-free C–H Borylation and Hydroboration of Indoles

[Image: see text] The C–H borylation and hydroboration reactions have emerged as promising synthetic tools to construct organoboron compounds. Organoboron compounds of N-heterocycles, particularly indole derivatives, have found widespread application in a variety of fields. As a result, considerable advancement in the area of C–H borylation and hydroboration reactions of indoles was observed in the last few decades. Among the various synthetic methods applied, the metal-free approach has received special attention. This mini-review discusses the recent progress in the area of C–H borylation and hydroboration reactions of indoles under metal-free conditions, their scope, and brief mechanistic studies.