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C(sp(2))–H Hydroxylation via Catalytic 1,4-Ni Migration with N(2)O

[Image: see text] Herein, we report a Ni-catalyzed C(sp(2))–H hydroxylation of aryl bromides with N(2)O as an oxygen-atom donor. The reaction is enabled by a 1,4-Ni translocation that results in ipso/ortho difunctionalized products. Regioselectivity and stereocontrol are dictated by a judicious choi...

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Detalles Bibliográficos
Autores principales:	Zhang, Huihui, Rodrigalvarez, Jesus, Martin, Ruben
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2023
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10586377/ https://www.ncbi.nlm.nih.gov/pubmed/37531410 http://dx.doi.org/10.1021/jacs.3c07018

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