Calorimetric evidence for two phase transitions in Ba(1−x)K(x)Fe(2)As(2) with fermion pairing and quadrupling states

Materials that break multiple symmetries allow the formation of four-fermion condensates above the superconducting critical temperature (T(c)). Such states can be stabilized by phase fluctuations. Recently, a fermionic quadrupling condensate that breaks the Z(2) time-reversal symmetry was reported in Ba(1−x)K(x)Fe(2)As(2). A phase transition to the new state of matter should be accompanied by a specific heat anomaly at the critical temperature where Z(2) time-reversal symmetry is broken ([Formula: see text] ). Here, we report on detecting two anomalies in the specific heat of Ba(1−x)K(x)Fe(2)As(2) at zero magnetic field. The anomaly at the higher temperature is accompanied by the appearance of a spontaneous Nernst effect, indicating the breakdown of Z(2) symmetry. The second anomaly at the lower temperature coincides with the transition to a zero-resistance state, indicating the onset of superconductivity. Our data provide the first example of the appearance of a specific heat anomaly above the superconducting phase transition associated with the broken time-reversal symmetry due to the formation of the novel fermion order.