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Two Total Syntheses of Trigoxyphins K and L

[Image: see text] Two total syntheses are presented for trigoxyphins K and L, tricyclic terpenoids from Trigonostemon xyphophylloides. The first proceeds via electrophlic cyclization in A/C-ring substrates to close the B ring at C4–C5 and then (1)O(2)-mediated hydroxybutenolide formation to trigoxyp...

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Detalles Bibliográficos
Autores principales:	Li, Shuyang, O’Hanlon, Jack A., Mattimoe, Andrew, Pickford, Helena D., Harwood, Lucy A., Wong, Luet L., Robertson, Jeremy
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2023
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10594648/ https://www.ncbi.nlm.nih.gov/pubmed/37801002 http://dx.doi.org/10.1021/acs.orglett.3c02796

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