Carboxylate Catalysis: A Catalytic O-Silylative Aldol Reaction of Aldehydes and Ethyl Diazoacetate

[Image: see text] A mild catalytic variant of the aldol reaction between ethyl diazoacetate and aldehydes is described using a combination of N,O-bis(trimethylsilyl)acetamide and catalytic tetramethylammonium pivalate as catalyst. The reaction proceeds rapidly at ambient temperature to afford the O-...

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Detalles Bibliográficos
Autores principales: Riuttamäki, Saara, Bannykh, Anton, Pihko, Petri M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10594658/
https://www.ncbi.nlm.nih.gov/pubmed/37768196
http://dx.doi.org/10.1021/acs.joc.3c01304

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10594658/
https://www.ncbi.nlm.nih.gov/pubmed/37768196
http://dx.doi.org/10.1021/acs.joc.3c01304

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