Zeolitic imidazolate framework-8/polyaniline nanocomposite-based electrochemical sensor for sensitive detection of imidaclothiz

Imidaclothiz (IMZ) is a class of neonicotinoid insecticide which can pose potential threat to human health and be frequently detected in water and foods. Herein, a zeolitic imidazolate framework-8/polyaniline (ZIF-8/PANI) nanocomposite has been modified on the surface of glassy carbon electrode (GCE) for the electrochemical determination of IMZ, and the electrochemical detection performance of the modified electrode was investigated by cyclic voltammetry (CV) and square wave voltammetry (SWV). With the large surface area of ZIF-8 and great electric conductivity of PANI, the ZIF-8/PANI-modified electrode showed a high catalytic performance towards IMZ reduction in PBS. Under the optimized conditions, the linear range was from 1.0 × 10(−7) to 1.0 × 10(−5) mol/L and the limit of detection was as low as 2.5 × 10(−8) mol/L (S/N = 3). In addition, the developed sensor displayed high reproducibility, excellent stability, and applicability in real vegetable sample analysis, indicating that the proposed method offered an alternative approach for IMZ residues analysis. GRAPHICAL ABSTRACT: [Image: see text] SUPPLEMENTARY INFORMATION: The online version contains supplementary material available at 10.2116/analsci.21P063.