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Effect of Polymer Waste Mix Filler on Polymer Concrete Composites

[Image: see text] The hazards of polymer waste and emitted gas on the environment pose a global challenge. As a trial to control this, the current work aims to reuse the polymer waste mix (PM) as fillers in calcium silicate to prepare new composites of environmentally friendly polymer concrete. PM w...

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Autores principales: Abdelsattar, Doha E., El-Demerdash, Safinaz H., Zaki, Elsayed G., Dhmees, Abdelghaffar S., Azab, Mostafa A., Elsaeed, Shimaa M., Kandil, Usama F., Naguib, Hamdy M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10601057/
https://www.ncbi.nlm.nih.gov/pubmed/37901558
http://dx.doi.org/10.1021/acsomega.3c05739
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author Abdelsattar, Doha E.
El-Demerdash, Safinaz H.
Zaki, Elsayed G.
Dhmees, Abdelghaffar S.
Azab, Mostafa A.
Elsaeed, Shimaa M.
Kandil, Usama F.
Naguib, Hamdy M.
author_facet Abdelsattar, Doha E.
El-Demerdash, Safinaz H.
Zaki, Elsayed G.
Dhmees, Abdelghaffar S.
Azab, Mostafa A.
Elsaeed, Shimaa M.
Kandil, Usama F.
Naguib, Hamdy M.
author_sort Abdelsattar, Doha E.
collection PubMed
description [Image: see text] The hazards of polymer waste and emitted gas on the environment pose a global challenge. As a trial to control this, the current work aims to reuse the polymer waste mix (PM) as fillers in calcium silicate to prepare new composites of environmentally friendly polymer concrete. PM was first subjected to treatment to obtain treated PM (TPM) and then was filled in new dicalcium silicate cement with different concentrations. The microstructural characterizations declare the successful preparation of the dicalcium silicate base material. After the curing reaction, the precipitated carbonate main product is responsible for the gained properties. The CO(2) uptake% in the proposed composites reached 16.6%, referring to the successful storage of CO(2) gas during curing. The treatment reaction led to an increase in the flexural and compression strengths due to the strengthening of the polymer waste mix–cement interface; the strengths were increased gradually with more contents of TPM fillers. 7% TPM–cement concentration achieved the highest flexural strength and compression strength of10.2 and 12.7%, respectively, compared with blank cement. The used polymer improved slightly the pull-off force of the prepared cement, and 7 and 5% TPM–cement composites have the maximum values. All the proposed composites passed the impact testing without failure, where the combination between the polymer waste and silicate cement resulted in a stable composite surface. Compared with the blank, the different concentrations of TPM–cement composites show more stability against water absorption. In addition, the proposed composites and blank cement have a very low carbon dioxide emission. The ability to recycle the polymer waste, form new type of low-energy silicate, improve the mechanical and surface properties, uptake CO(2) gas, and reduce gas emission makes the proposed polymer waste mix–cement composites as environmentally friendly construction products.
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spelling pubmed-106010572023-10-27 Effect of Polymer Waste Mix Filler on Polymer Concrete Composites Abdelsattar, Doha E. El-Demerdash, Safinaz H. Zaki, Elsayed G. Dhmees, Abdelghaffar S. Azab, Mostafa A. Elsaeed, Shimaa M. Kandil, Usama F. Naguib, Hamdy M. ACS Omega [Image: see text] The hazards of polymer waste and emitted gas on the environment pose a global challenge. As a trial to control this, the current work aims to reuse the polymer waste mix (PM) as fillers in calcium silicate to prepare new composites of environmentally friendly polymer concrete. PM was first subjected to treatment to obtain treated PM (TPM) and then was filled in new dicalcium silicate cement with different concentrations. The microstructural characterizations declare the successful preparation of the dicalcium silicate base material. After the curing reaction, the precipitated carbonate main product is responsible for the gained properties. The CO(2) uptake% in the proposed composites reached 16.6%, referring to the successful storage of CO(2) gas during curing. The treatment reaction led to an increase in the flexural and compression strengths due to the strengthening of the polymer waste mix–cement interface; the strengths were increased gradually with more contents of TPM fillers. 7% TPM–cement concentration achieved the highest flexural strength and compression strength of10.2 and 12.7%, respectively, compared with blank cement. The used polymer improved slightly the pull-off force of the prepared cement, and 7 and 5% TPM–cement composites have the maximum values. All the proposed composites passed the impact testing without failure, where the combination between the polymer waste and silicate cement resulted in a stable composite surface. Compared with the blank, the different concentrations of TPM–cement composites show more stability against water absorption. In addition, the proposed composites and blank cement have a very low carbon dioxide emission. The ability to recycle the polymer waste, form new type of low-energy silicate, improve the mechanical and surface properties, uptake CO(2) gas, and reduce gas emission makes the proposed polymer waste mix–cement composites as environmentally friendly construction products. American Chemical Society 2023-10-09 /pmc/articles/PMC10601057/ /pubmed/37901558 http://dx.doi.org/10.1021/acsomega.3c05739 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Abdelsattar, Doha E.
El-Demerdash, Safinaz H.
Zaki, Elsayed G.
Dhmees, Abdelghaffar S.
Azab, Mostafa A.
Elsaeed, Shimaa M.
Kandil, Usama F.
Naguib, Hamdy M.
Effect of Polymer Waste Mix Filler on Polymer Concrete Composites
title Effect of Polymer Waste Mix Filler on Polymer Concrete Composites
title_full Effect of Polymer Waste Mix Filler on Polymer Concrete Composites
title_fullStr Effect of Polymer Waste Mix Filler on Polymer Concrete Composites
title_full_unstemmed Effect of Polymer Waste Mix Filler on Polymer Concrete Composites
title_short Effect of Polymer Waste Mix Filler on Polymer Concrete Composites
title_sort effect of polymer waste mix filler on polymer concrete composites
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10601057/
https://www.ncbi.nlm.nih.gov/pubmed/37901558
http://dx.doi.org/10.1021/acsomega.3c05739
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