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Synthesis, Characterization, and Energetic Properties of Nitrate Ester Acrylate Polymer
[Image: see text] An energetic nitrate ester acrylate monomer (4) was synthesized in a total yield of 68% and polymerized to form the energetic nitrate ester acrylate polymer (NEAP). Compound 4 is a liquid at room temperature with a melting point of −8.6 °C and NEAP is a solid with a glass-transitio...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10601433/ https://www.ncbi.nlm.nih.gov/pubmed/37901546 http://dx.doi.org/10.1021/acsomega.3c02725 |
| _version_ | 1785126195941081088 |
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| author | Kuehl, Valerie A. Schmalzer, Andrew M. Snyder, Christopher J. Chavez, David E. |
| author_facet | Kuehl, Valerie A. Schmalzer, Andrew M. Snyder, Christopher J. Chavez, David E. |
| author_sort | Kuehl, Valerie A. |
| collection | PubMed |
| description | [Image: see text] An energetic nitrate ester acrylate monomer (4) was synthesized in a total yield of 68% and polymerized to form the energetic nitrate ester acrylate polymer (NEAP). Compound 4 is a liquid at room temperature with a melting point of −8.6 °C and NEAP is a solid with a glass-transition temperature of −8.8 °C. Intermediates leading to 4 and NEAP were characterized by high-resolution mass spectrometry, elemental analysis, Fourier transform infrared spectroscopy, and proton and carbon nuclear magnetic resonance spectroscopies ((1)H and (13)C{(1)H} NMR). Both 4 and NEAP have electrostatic discharge, friction, and impact sensitivities comparable to those of trinitrotoluene, making NEAP a potential candidate for advanced energetic formulations. |
| format | Online Article Text |
| id | pubmed-10601433 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2023 |
| publisher | American Chemical Society |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-106014332023-10-27 Synthesis, Characterization, and Energetic Properties of Nitrate Ester Acrylate Polymer Kuehl, Valerie A. Schmalzer, Andrew M. Snyder, Christopher J. Chavez, David E. ACS Omega [Image: see text] An energetic nitrate ester acrylate monomer (4) was synthesized in a total yield of 68% and polymerized to form the energetic nitrate ester acrylate polymer (NEAP). Compound 4 is a liquid at room temperature with a melting point of −8.6 °C and NEAP is a solid with a glass-transition temperature of −8.8 °C. Intermediates leading to 4 and NEAP were characterized by high-resolution mass spectrometry, elemental analysis, Fourier transform infrared spectroscopy, and proton and carbon nuclear magnetic resonance spectroscopies ((1)H and (13)C{(1)H} NMR). Both 4 and NEAP have electrostatic discharge, friction, and impact sensitivities comparable to those of trinitrotoluene, making NEAP a potential candidate for advanced energetic formulations. American Chemical Society 2023-10-13 /pmc/articles/PMC10601433/ /pubmed/37901546 http://dx.doi.org/10.1021/acsomega.3c02725 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/). |
| spellingShingle | Kuehl, Valerie A. Schmalzer, Andrew M. Snyder, Christopher J. Chavez, David E. Synthesis, Characterization, and Energetic Properties of Nitrate Ester Acrylate Polymer |
| title | Synthesis, Characterization,
and Energetic Properties
of Nitrate Ester Acrylate Polymer |
| title_full | Synthesis, Characterization,
and Energetic Properties
of Nitrate Ester Acrylate Polymer |
| title_fullStr | Synthesis, Characterization,
and Energetic Properties
of Nitrate Ester Acrylate Polymer |
| title_full_unstemmed | Synthesis, Characterization,
and Energetic Properties
of Nitrate Ester Acrylate Polymer |
| title_short | Synthesis, Characterization,
and Energetic Properties
of Nitrate Ester Acrylate Polymer |
| title_sort | synthesis, characterization,
and energetic properties
of nitrate ester acrylate polymer |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10601433/ https://www.ncbi.nlm.nih.gov/pubmed/37901546 http://dx.doi.org/10.1021/acsomega.3c02725 |
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