Metal Complexes in the Synthesis of Biodegradable Polymers: Achievements and Prospects

This review describes recent advances in the synthesis of homopolymers of lactide and related cyclic esters via ring-opening polymerization (ROP) in the presence of metal complexes based on group 1, 2, 4, 12, 13 and 14 metals. Particular attention is paid to the influence of the initiator structure...

Descripción completa

Detalles Bibliográficos
Autores principales: Mankaev, Badma N., Karlov, Sergey S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10608263/
https://www.ncbi.nlm.nih.gov/pubmed/37895663
http://dx.doi.org/10.3390/ma16206682
_version_ 1785127738760232960
author Mankaev, Badma N.
Karlov, Sergey S.
author_facet Mankaev, Badma N.
Karlov, Sergey S.
author_sort Mankaev, Badma N.
collection PubMed
description This review describes recent advances in the synthesis of homopolymers of lactide and related cyclic esters via ring-opening polymerization (ROP) in the presence of metal complexes based on group 1, 2, 4, 12, 13 and 14 metals. Particular attention is paid to the influence of the initiator structure on the properties of the obtaining homo- and copolymers. Also, a separate chapter is devoted to the study of metal complexes in the synthesis of copolymers of lactide and lactones. This review highlights the efforts made over the last ten years or so, and shows how main-group metals have received increasing attention in the field of the polymerization of lactide and related cyclic esters.
format Online
Article
Text
id pubmed-10608263
institution National Center for Biotechnology Information
language English
publishDate 2023
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-106082632023-10-28 Metal Complexes in the Synthesis of Biodegradable Polymers: Achievements and Prospects Mankaev, Badma N. Karlov, Sergey S. Materials (Basel) Review This review describes recent advances in the synthesis of homopolymers of lactide and related cyclic esters via ring-opening polymerization (ROP) in the presence of metal complexes based on group 1, 2, 4, 12, 13 and 14 metals. Particular attention is paid to the influence of the initiator structure on the properties of the obtaining homo- and copolymers. Also, a separate chapter is devoted to the study of metal complexes in the synthesis of copolymers of lactide and lactones. This review highlights the efforts made over the last ten years or so, and shows how main-group metals have received increasing attention in the field of the polymerization of lactide and related cyclic esters. MDPI 2023-10-13 /pmc/articles/PMC10608263/ /pubmed/37895663 http://dx.doi.org/10.3390/ma16206682 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Review
Mankaev, Badma N.
Karlov, Sergey S.
Metal Complexes in the Synthesis of Biodegradable Polymers: Achievements and Prospects
title Metal Complexes in the Synthesis of Biodegradable Polymers: Achievements and Prospects
title_full Metal Complexes in the Synthesis of Biodegradable Polymers: Achievements and Prospects
title_fullStr Metal Complexes in the Synthesis of Biodegradable Polymers: Achievements and Prospects
title_full_unstemmed Metal Complexes in the Synthesis of Biodegradable Polymers: Achievements and Prospects
title_short Metal Complexes in the Synthesis of Biodegradable Polymers: Achievements and Prospects
title_sort metal complexes in the synthesis of biodegradable polymers: achievements and prospects
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10608263/
https://www.ncbi.nlm.nih.gov/pubmed/37895663
http://dx.doi.org/10.3390/ma16206682
work_keys_str_mv AT mankaevbadman metalcomplexesinthesynthesisofbiodegradablepolymersachievementsandprospects
AT karlovsergeys metalcomplexesinthesynthesisofbiodegradablepolymersachievementsandprospects

Ejemplares similares