Phase Equilibria of the V-Ti-Fe System and Its Applications in the Design of Novel Hydrogen Permeable Alloys

The precise liquidus projection of the V-Ti-Fe system are crucial for designing high-performance hydrogen permeation alloys, but there are still many controversies in the research of this system. To this end, this article first uses the CALPHAD (CALculation of PHAse Diagrams) method to reconstruct the alloy phase diagram and compares and analyses existing experimental data, confirming that the newly constructed phase diagram in this article has good reliability and accuracy. Second, this obtained phase diagram was applied to the subsequent development process of hydrogen permeation alloys, and the (Ti(65)Fe(35))(100−x)V(x) (x = 0, 2.5, 5, 10, 15, 25) alloys with dual-phase {bcc-(V, Ti) + TiFe} structure were successfully explored. In particular, the alloys with x values equal to 2.5 at.% and 5 at.% exhibit relatively high hydrogen permeability. Third, to further increase the H(2) flux permeation through the alloys, a 500-mm-long tubular (Ti(65)Fe(35))(95)V(5) membrane for hydrogen permeation was prepared for the first time. Hydrogen permeation testing showed that this membrane had a very high H(2) flux (4.06 mL min(−1)), which is ca. 6.7 times greater than the plate-like counterpart (0.61 mL min(−1)) under the same test conditions. This work not only indicates the reliability of the obtained V-Ti-Fe phase diagram in developing new hydrogen permeation alloys, but also demonstrates that preparing tubular membranes is one of the most important means of improving H(2) flux.