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Modified Polyethylene Foams for Insulation Systems

Effective insulation of buildings and other industrial objects requires the use of materials and system solutions that ensure maximum uniformity and density of insulation shells. The study focuses on the development of insulation systems based on expanded polyethylene and, in particular, on the deve...

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Autores principales: Thomas, Sabu, Ter-Zakaryan, Karapet Armenovich, Zhukov, Aleksey Dmitrievich, Bessonov, Igor’ Vyacheslavovich
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10610372/
https://www.ncbi.nlm.nih.gov/pubmed/37896348
http://dx.doi.org/10.3390/polym15204104
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author Thomas, Sabu
Ter-Zakaryan, Karapet Armenovich
Zhukov, Aleksey Dmitrievich
Bessonov, Igor’ Vyacheslavovich
author_facet Thomas, Sabu
Ter-Zakaryan, Karapet Armenovich
Zhukov, Aleksey Dmitrievich
Bessonov, Igor’ Vyacheslavovich
author_sort Thomas, Sabu
collection PubMed
description Effective insulation of buildings and other industrial objects requires the use of materials and system solutions that ensure maximum uniformity and density of insulation shells. The study focuses on the development of insulation systems based on expanded polyethylene and, in particular, on the development of modified polyethylene with reduced flammability containing a flame-retardant modified montmorillonite clay, which does not hinder gas formation, and silicate nanofillers in layered construction. Active experiments based on mathematical design methods allowed us to establish an analytical relationship between flame-retardant and modifier consumption and extruder pressure and response functions: average density of polyethylene foam and flammability criterion. The flammability criterion was taken as the oxygen index of the modified polyethylene foam. A foaming agent masterbatch was used as the flame retardant. Analytical optimization of mathematical models obtained as a result of active experiments allowed us to determine the optimal flame-retardant consumption, which was 3.7–3.8% of the polymer mass. Optimised systems for average density and oxygen index of flammability of modified polyethylene were obtained. A nomogram for predicting the material properties and selecting the composition, and an algorithm for a computer program for evaluating the properties of modified polyethylene foam as a function of the values of various factors, were developed. Taking into account the possible expansion of the scope of application of rolled polyethylene foam and seamless insulation shells based on it, possible solutions for insulation systems were studied using the program THERM, and a combined insulation system was adopted.
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spelling pubmed-106103722023-10-28 Modified Polyethylene Foams for Insulation Systems Thomas, Sabu Ter-Zakaryan, Karapet Armenovich Zhukov, Aleksey Dmitrievich Bessonov, Igor’ Vyacheslavovich Polymers (Basel) Article Effective insulation of buildings and other industrial objects requires the use of materials and system solutions that ensure maximum uniformity and density of insulation shells. The study focuses on the development of insulation systems based on expanded polyethylene and, in particular, on the development of modified polyethylene with reduced flammability containing a flame-retardant modified montmorillonite clay, which does not hinder gas formation, and silicate nanofillers in layered construction. Active experiments based on mathematical design methods allowed us to establish an analytical relationship between flame-retardant and modifier consumption and extruder pressure and response functions: average density of polyethylene foam and flammability criterion. The flammability criterion was taken as the oxygen index of the modified polyethylene foam. A foaming agent masterbatch was used as the flame retardant. Analytical optimization of mathematical models obtained as a result of active experiments allowed us to determine the optimal flame-retardant consumption, which was 3.7–3.8% of the polymer mass. Optimised systems for average density and oxygen index of flammability of modified polyethylene were obtained. A nomogram for predicting the material properties and selecting the composition, and an algorithm for a computer program for evaluating the properties of modified polyethylene foam as a function of the values of various factors, were developed. Taking into account the possible expansion of the scope of application of rolled polyethylene foam and seamless insulation shells based on it, possible solutions for insulation systems were studied using the program THERM, and a combined insulation system was adopted. MDPI 2023-10-16 /pmc/articles/PMC10610372/ /pubmed/37896348 http://dx.doi.org/10.3390/polym15204104 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Thomas, Sabu
Ter-Zakaryan, Karapet Armenovich
Zhukov, Aleksey Dmitrievich
Bessonov, Igor’ Vyacheslavovich
Modified Polyethylene Foams for Insulation Systems
title Modified Polyethylene Foams for Insulation Systems
title_full Modified Polyethylene Foams for Insulation Systems
title_fullStr Modified Polyethylene Foams for Insulation Systems
title_full_unstemmed Modified Polyethylene Foams for Insulation Systems
title_short Modified Polyethylene Foams for Insulation Systems
title_sort modified polyethylene foams for insulation systems
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10610372/
https://www.ncbi.nlm.nih.gov/pubmed/37896348
http://dx.doi.org/10.3390/polym15204104
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