Synthesis and Photocatalytic Activity of Novel Polycyclopentadithiophene

A novel π-conjugated polymer based on cyclopentadithiophene (CPDT) and poly(4,4′]-(((4Hcyclopenta[2,1-b:3,4-b′]dithiophene-4,4-diyl)bis(ethane-2,1-diyl))bis(oxy))bis(4-oxobutanoic acid)) (PCPDT-CO(2)H) was prepared as a sparingly soluble material. The generation of hydroxyl radicals from PCPDT-CO(2)...

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Autores principales: Zulkifli, Farah Zayanah Ahmad, Ito, Moeka, Uno, Takahiro, Kubo, Masataka
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10610433/
https://www.ncbi.nlm.nih.gov/pubmed/37896335
http://dx.doi.org/10.3390/polym15204091
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author Zulkifli, Farah Zayanah Ahmad
Ito, Moeka
Uno, Takahiro
Kubo, Masataka
author_facet Zulkifli, Farah Zayanah Ahmad
Ito, Moeka
Uno, Takahiro
Kubo, Masataka
author_sort Zulkifli, Farah Zayanah Ahmad
collection PubMed
description A novel π-conjugated polymer based on cyclopentadithiophene (CPDT) and poly(4,4′]-(((4Hcyclopenta[2,1-b:3,4-b′]dithiophene-4,4-diyl)bis(ethane-2,1-diyl))bis(oxy))bis(4-oxobutanoic acid)) (PCPDT-CO(2)H) was prepared as a sparingly soluble material. The generation of hydroxyl radicals from PCPDT-CO(2)H in water was confirmed by using coumarin as a hydroxyl radical indicator. Furthermore, PCPDT-CO(2)H was found to catalyze the oxidative hydroxylation of arylboronic acid and the oxidation of benzaldehyde, indicating that PCPDT-CO(2)H can be a promising candidate for metal-free and 100% organic heterogeneous photocatalysts.
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spelling pubmed-106104332023-10-28 Synthesis and Photocatalytic Activity of Novel Polycyclopentadithiophene Zulkifli, Farah Zayanah Ahmad Ito, Moeka Uno, Takahiro Kubo, Masataka Polymers (Basel) Article A novel π-conjugated polymer based on cyclopentadithiophene (CPDT) and poly(4,4′]-(((4Hcyclopenta[2,1-b:3,4-b′]dithiophene-4,4-diyl)bis(ethane-2,1-diyl))bis(oxy))bis(4-oxobutanoic acid)) (PCPDT-CO(2)H) was prepared as a sparingly soluble material. The generation of hydroxyl radicals from PCPDT-CO(2)H in water was confirmed by using coumarin as a hydroxyl radical indicator. Furthermore, PCPDT-CO(2)H was found to catalyze the oxidative hydroxylation of arylboronic acid and the oxidation of benzaldehyde, indicating that PCPDT-CO(2)H can be a promising candidate for metal-free and 100% organic heterogeneous photocatalysts. MDPI 2023-10-15 /pmc/articles/PMC10610433/ /pubmed/37896335 http://dx.doi.org/10.3390/polym15204091 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Zulkifli, Farah Zayanah Ahmad
Ito, Moeka
Uno, Takahiro
Kubo, Masataka
Synthesis and Photocatalytic Activity of Novel Polycyclopentadithiophene
title Synthesis and Photocatalytic Activity of Novel Polycyclopentadithiophene
title_full Synthesis and Photocatalytic Activity of Novel Polycyclopentadithiophene
title_fullStr Synthesis and Photocatalytic Activity of Novel Polycyclopentadithiophene
title_full_unstemmed Synthesis and Photocatalytic Activity of Novel Polycyclopentadithiophene
title_short Synthesis and Photocatalytic Activity of Novel Polycyclopentadithiophene
title_sort synthesis and photocatalytic activity of novel polycyclopentadithiophene
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10610433/
https://www.ncbi.nlm.nih.gov/pubmed/37896335
http://dx.doi.org/10.3390/polym15204091
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