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Analysis of the Effect of Network Structure and Disulfide Concentration on Vitrimer Properties

A set of five vitrimers with glass transition temperatures in the range of 80–90 °C were designed to assess the effect of the network structure and disulfide concentration on their dynamic and mechanical properties, and to find the best performing system overall compared to the commercial Araldite L...

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Detalles Bibliográficos
Autores principales: Azcune, Itxaso, Elorza, Edurne, Ruiz de Luzuriaga, Alaitz, Huegun, Arrate, Rekondo, Alaitz, Grande, Hans-Jürgen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10610872/
https://www.ncbi.nlm.nih.gov/pubmed/37896367
http://dx.doi.org/10.3390/polym15204123
Descripción
Sumario:A set of five vitrimers with glass transition temperatures in the range of 80–90 °C were designed to assess the effect of the network structure and disulfide concentration on their dynamic and mechanical properties, and to find the best performing system overall compared to the commercial Araldite LY1564/Aradur 3486 commercial thermoset system. Vitrimer networks were prepared by incorporating mono- and bifunctional epoxy reactive diluents and an amine chain extender into the Araldite LY1564/4-aminophenyldisulfide system.