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Harnessing Proton-Coupled Electron Transfer for Hydrogenation of Aza-Arenes: Photochemistry of Quinoxaline Derivatives in Methanol

[Image: see text] Three quinoxaline derivatives are investigated both experimentally and theoretically to assess their ability for the methanol oxidation and harvesting of hydrogen. In inert solvents, the nonplanar compounds exhibit very weak fluorescence from the lowest excited singlet state, where...

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Detalles Bibliográficos
Autores principales: Morawski, Olaf W., Gawryś, Paweł, Sobolewski, Andrzej L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10614181/
https://www.ncbi.nlm.nih.gov/pubmed/37842877
http://dx.doi.org/10.1021/acs.jpca.3c05077