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Ligand effect of cyclometallated iridium(iii) complexes on N-alkylation of amines in hydrogen borrowing reactions

Dinuclear iridium complexes with the general formula (C^N)(2)Ir(μ-Cl)(2)Ir(C^N)(2) (C^N = bidentate ligand with carbon and nitrogen donor atoms) were prepared and used in catalytic systems for N-alkylation of amines through the hydrogen borrowing pathway. Triphenylphosphine derivatives were used as...

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Detalles Bibliográficos
Autores principales: Chen, Yi-Sheng, Chiu, Siang-Yu, Li, Chia-Ying, Chen, Tsun-Ren, Chen, Jhy-Der
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10617371/
https://www.ncbi.nlm.nih.gov/pubmed/37915445
http://dx.doi.org/10.1039/d3ra07184g