Robust 2D layered MXene matrix–boron carbide hybrid films for neutron radiation shielding

Large-scale fabrication of neutron-shielding films with flexible or complex shapes is challenging. Uniform and high boron carbide (B(4)C) filler loads with sufficient workability are needed to achieve good neutron-absorption capacity. Here, we show that a two-dimensional (2D) Ti(3)C(2)T(x) MXene hybrid film with homogeneously distributed B(4)C particles exhibits high mechanical flexibility and anomalous neutron-shielding properties. Layered and solution-processable 2D Ti(3)C(2)T(x) MXene flakes serve as an ideal robust and flexible matrix for high-content B(4)C fillers (60 wt.%). In addition, the preparation of a scalable neutron shielding MXene/B(4)C hybrid paint is demonstrated. This composite can be directly integrated with various large-scale surfaces (e.g., stainless steel, glass, and nylon). Because of their low thickness, simple and scalable preparation method, and an absorption capacity of 39.8% for neutrons emitted from a (241)Am–(9)Be source, the 2D Ti(3)C(2)T(x) MXene hybrid films are promising candidates for use in wearable and lightweight applications.