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Persulfate-assisted heterogeneous photocatalytic degradation of furfural from aqueous solutions using TiO(2)–ZnO/biochar composite
This study evaluated the performance of TiO(2)–ZnO/biochar as activator of persulfate (PS) for degradation of furfural. After the successful synthesis of the catalyst, X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM) methods were used to...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Elsevier
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10618828/ https://www.ncbi.nlm.nih.gov/pubmed/37920492 http://dx.doi.org/10.1016/j.heliyon.2023.e21421 |
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author | Hasanzadeh, Maryam Ghaedrahmat, Zeinab Kayedi, Neda Haghighi Fard, Neamatollah Jaafarzadeh Azari, Ali Afsharizadeh, Maryam |
author_facet | Hasanzadeh, Maryam Ghaedrahmat, Zeinab Kayedi, Neda Haghighi Fard, Neamatollah Jaafarzadeh Azari, Ali Afsharizadeh, Maryam |
author_sort | Hasanzadeh, Maryam |
collection | PubMed |
description | This study evaluated the performance of TiO(2)–ZnO/biochar as activator of persulfate (PS) for degradation of furfural. After the successful synthesis of the catalyst, X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM) methods were used to investigate the properties of TiO(2)–ZnO/biochar. The findings of this research suggests that under optimal conditions (pH = 3, catalyst dosage = 1 g/L, persulfate concentration = 1.2 mM, and furfural concentration = 10 mg/L), the PS/Catalysts/UV system can remove 96 % of furfural within 15 min. Under ideal conditions, the experimental results fit well with the first-order kinetic model (R(2) > 0.95), and the rate constant (K(obs)) was derived as 0.195 min(−1). The quenching experiments provided further insights that confirmed the participation of SO(4)°(−) and OH° radicals in the degradation process. Nevertheless, the evidence strongly supports the idea that SO(4)°(−) plays a more prominent and dominant role as the primary radical species responsible for furfural degradation. Based on the obtained results, it can be concluded that the PS/Catalysts/UV system has an appropriate ability to remove furfural from aqueous solutions, which suggests promising perspectives for its practical application in pollutant treatment scenarios. |
format | Online Article Text |
id | pubmed-10618828 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | Elsevier |
record_format | MEDLINE/PubMed |
spelling | pubmed-106188282023-11-02 Persulfate-assisted heterogeneous photocatalytic degradation of furfural from aqueous solutions using TiO(2)–ZnO/biochar composite Hasanzadeh, Maryam Ghaedrahmat, Zeinab Kayedi, Neda Haghighi Fard, Neamatollah Jaafarzadeh Azari, Ali Afsharizadeh, Maryam Heliyon Research Article This study evaluated the performance of TiO(2)–ZnO/biochar as activator of persulfate (PS) for degradation of furfural. After the successful synthesis of the catalyst, X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM) methods were used to investigate the properties of TiO(2)–ZnO/biochar. The findings of this research suggests that under optimal conditions (pH = 3, catalyst dosage = 1 g/L, persulfate concentration = 1.2 mM, and furfural concentration = 10 mg/L), the PS/Catalysts/UV system can remove 96 % of furfural within 15 min. Under ideal conditions, the experimental results fit well with the first-order kinetic model (R(2) > 0.95), and the rate constant (K(obs)) was derived as 0.195 min(−1). The quenching experiments provided further insights that confirmed the participation of SO(4)°(−) and OH° radicals in the degradation process. Nevertheless, the evidence strongly supports the idea that SO(4)°(−) plays a more prominent and dominant role as the primary radical species responsible for furfural degradation. Based on the obtained results, it can be concluded that the PS/Catalysts/UV system has an appropriate ability to remove furfural from aqueous solutions, which suggests promising perspectives for its practical application in pollutant treatment scenarios. Elsevier 2023-10-21 /pmc/articles/PMC10618828/ /pubmed/37920492 http://dx.doi.org/10.1016/j.heliyon.2023.e21421 Text en © 2023 The Authors https://creativecommons.org/licenses/by-nc-nd/4.0/This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/). |
spellingShingle | Research Article Hasanzadeh, Maryam Ghaedrahmat, Zeinab Kayedi, Neda Haghighi Fard, Neamatollah Jaafarzadeh Azari, Ali Afsharizadeh, Maryam Persulfate-assisted heterogeneous photocatalytic degradation of furfural from aqueous solutions using TiO(2)–ZnO/biochar composite |
title | Persulfate-assisted heterogeneous photocatalytic degradation of furfural from aqueous solutions using TiO(2)–ZnO/biochar composite |
title_full | Persulfate-assisted heterogeneous photocatalytic degradation of furfural from aqueous solutions using TiO(2)–ZnO/biochar composite |
title_fullStr | Persulfate-assisted heterogeneous photocatalytic degradation of furfural from aqueous solutions using TiO(2)–ZnO/biochar composite |
title_full_unstemmed | Persulfate-assisted heterogeneous photocatalytic degradation of furfural from aqueous solutions using TiO(2)–ZnO/biochar composite |
title_short | Persulfate-assisted heterogeneous photocatalytic degradation of furfural from aqueous solutions using TiO(2)–ZnO/biochar composite |
title_sort | persulfate-assisted heterogeneous photocatalytic degradation of furfural from aqueous solutions using tio(2)–zno/biochar composite |
topic | Research Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10618828/ https://www.ncbi.nlm.nih.gov/pubmed/37920492 http://dx.doi.org/10.1016/j.heliyon.2023.e21421 |
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