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To Bond or Not to Bond: Metal–Metal Interaction in Heterobimetallic Rare-Earth Metal–Silver Complexes
[Image: see text] The reaction of 2,4-(t)Bu(2)-6-(PPh(2))PhOH (HOAr(P)) with silver(I) triflate in a 3:1 molar ratio gave the mononuclear coinage metal complex (HOAr(P)-κP)(3)Ag(I)OTf (1). Treatment of HOAr(P) with Ln(III)[N(SiMe(3))(2)](3) (Ln = La, Sm, Y, Yb) in a 3:1 molar ratio yielded the monon...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10618923/ https://www.ncbi.nlm.nih.gov/pubmed/37851537 http://dx.doi.org/10.1021/acs.inorgchem.3c02377 |