Design Strategies for Luminescent Titanocenes: Improving the Photoluminescence and Photostability of Arylethynyltitanocenes

[Image: see text] Complexes that undergo ligand-to-metal charge transfer (LMCT) to d(0) metals are of interest as possible photocatalysts. Cp(2)Ti(C(2)Ph)(2) (where C(2)Ph = phenylethynyl) was reported to be weakly emissive in room-temperature (RT) fluid solution from its phenylethynyl-to-Ti (3)LMCT...

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Detalles Bibliográficos
Autores principales: Barker, Matilda, Whittemore, Thomas J., London, Henry C., Sledesky, Jack M., Harris, Elizabeth A., Smith Pellizzeri, Tiffany M., McMillen, Colin D., Wagenknecht, Paul S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10618925/
https://www.ncbi.nlm.nih.gov/pubmed/37831503
http://dx.doi.org/10.1021/acs.inorgchem.3c02712

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