The borderless world of chemical bonding across the van der Waals crust and the valence region

The definition of the van der Waals crust as the spherical section between the atomic radius and the van der Waals radius of an element is discussed and a survey of the application of the penetration index between two interacting atoms in a wide variety of covalent, polar, coordinative or noncovalen...

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Detalles Bibliográficos
Autores principales: Echeverría, Jorge, Alvarez, Santiago
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10619631/
https://www.ncbi.nlm.nih.gov/pubmed/37920358
http://dx.doi.org/10.1039/d3sc02238b
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author Echeverría, Jorge
Alvarez, Santiago
author_facet Echeverría, Jorge
Alvarez, Santiago
author_sort Echeverría, Jorge
collection PubMed
description The definition of the van der Waals crust as the spherical section between the atomic radius and the van der Waals radius of an element is discussed and a survey of the application of the penetration index between two interacting atoms in a wide variety of covalent, polar, coordinative or noncovalent bonding situations is presented. It is shown that this newly defined parameter permits the comparison of bonding between pairs of atoms in structural and computational studies independently of the atom sizes.
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spelling pubmed-106196312023-11-02 The borderless world of chemical bonding across the van der Waals crust and the valence region Echeverría, Jorge Alvarez, Santiago Chem Sci Chemistry The definition of the van der Waals crust as the spherical section between the atomic radius and the van der Waals radius of an element is discussed and a survey of the application of the penetration index between two interacting atoms in a wide variety of covalent, polar, coordinative or noncovalent bonding situations is presented. It is shown that this newly defined parameter permits the comparison of bonding between pairs of atoms in structural and computational studies independently of the atom sizes. The Royal Society of Chemistry 2023-07-06 /pmc/articles/PMC10619631/ /pubmed/37920358 http://dx.doi.org/10.1039/d3sc02238b Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Echeverría, Jorge
Alvarez, Santiago
The borderless world of chemical bonding across the van der Waals crust and the valence region
title The borderless world of chemical bonding across the van der Waals crust and the valence region
title_full The borderless world of chemical bonding across the van der Waals crust and the valence region
title_fullStr The borderless world of chemical bonding across the van der Waals crust and the valence region
title_full_unstemmed The borderless world of chemical bonding across the van der Waals crust and the valence region
title_short The borderless world of chemical bonding across the van der Waals crust and the valence region
title_sort borderless world of chemical bonding across the van der waals crust and the valence region
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10619631/
https://www.ncbi.nlm.nih.gov/pubmed/37920358
http://dx.doi.org/10.1039/d3sc02238b
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