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Effect on Improving CO(2) Sensor Properties: Combination of HPTS and γ-Fe(2)O(3)@ZnO Bioactive Glass
[Image: see text] 8-Hydroxypyrene-1,3,6-trisulfonic acid (HPTS) dye, a fluorescent dye often used as a pH indicator, is embedded within the bioactive glass matrix and undergoes changes in its fluorescent properties when exposed to carbon dioxide (CO(2)). The aim of the current study is to investigat...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10620782/ https://www.ncbi.nlm.nih.gov/pubmed/37929109 http://dx.doi.org/10.1021/acsomega.3c05361 |
Sumario: | [Image: see text] 8-Hydroxypyrene-1,3,6-trisulfonic acid (HPTS) dye, a fluorescent dye often used as a pH indicator, is embedded within the bioactive glass matrix and undergoes changes in its fluorescent properties when exposed to carbon dioxide (CO(2)). The aim of the current study is to investigate the use of bioactive glass (BG) particles containing γ-Fe(2)O(3)@ZnO to enhance the CO(2) sensitivity of HPTS. X-ray diffraction, Fourier transform infrared, scanning electron microscopy, and photoluminescence spectroscopies were used to characterize the sol–gel synthesized powders. The sensing slides were prepared in the form of a thin film by immobilizing the fluorescent dye and γ-Fe(2)O(3)@ZnO-based additives into the poly(methyl methacrylate) matrix. The addition of γ-Fe(2)O(3)@ZnO nanoparticles with bioactive glass additives to the HPTS improves the performance characteristics of the sensor, including the linear response range, relative signal variation, and sensitivity. Meanwhile, the CO(2) sensitivities were measured as 10.22, 7.73, 16.56, 17.82, 19.58, and 42.40 for the undoped form and M, M@ZnO, 5M@ZnO-BG, 10M@ZnO-BG, and 20M@ZnO-BG NP-doped forms of the HPTS-based thin films, respectively. The response and recovery times of the HPTS-based sensing slide along with 20M@ZnO-BG NPs have been measured as 44 and 276 s, respectively. The γ-Fe(2)O(3)/ZnO-containing BG particle-doped HPTS composites can be used as a promising sensor agent in the detection of CO(2) gas in various fields such as environmental monitoring, medical diagnostics, and industrial processes. |
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