Cargando…

Effect on Improving CO(2) Sensor Properties: Combination of HPTS and γ-Fe(2)O(3)@ZnO Bioactive Glass

[Image: see text] 8-Hydroxypyrene-1,3,6-trisulfonic acid (HPTS) dye, a fluorescent dye often used as a pH indicator, is embedded within the bioactive glass matrix and undergoes changes in its fluorescent properties when exposed to carbon dioxide (CO(2)). The aim of the current study is to investigat...

Descripción completa

Detalles Bibliográficos
Autores principales: Oguzlar, Sibel, Zeyrek Ongun, Merve, Deliormanlı, Aylin M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10620782/
https://www.ncbi.nlm.nih.gov/pubmed/37929109
http://dx.doi.org/10.1021/acsomega.3c05361
_version_ 1785130274962538496
author Oguzlar, Sibel
Zeyrek Ongun, Merve
Deliormanlı, Aylin M.
author_facet Oguzlar, Sibel
Zeyrek Ongun, Merve
Deliormanlı, Aylin M.
author_sort Oguzlar, Sibel
collection PubMed
description [Image: see text] 8-Hydroxypyrene-1,3,6-trisulfonic acid (HPTS) dye, a fluorescent dye often used as a pH indicator, is embedded within the bioactive glass matrix and undergoes changes in its fluorescent properties when exposed to carbon dioxide (CO(2)). The aim of the current study is to investigate the use of bioactive glass (BG) particles containing γ-Fe(2)O(3)@ZnO to enhance the CO(2) sensitivity of HPTS. X-ray diffraction, Fourier transform infrared, scanning electron microscopy, and photoluminescence spectroscopies were used to characterize the sol–gel synthesized powders. The sensing slides were prepared in the form of a thin film by immobilizing the fluorescent dye and γ-Fe(2)O(3)@ZnO-based additives into the poly(methyl methacrylate) matrix. The addition of γ-Fe(2)O(3)@ZnO nanoparticles with bioactive glass additives to the HPTS improves the performance characteristics of the sensor, including the linear response range, relative signal variation, and sensitivity. Meanwhile, the CO(2) sensitivities were measured as 10.22, 7.73, 16.56, 17.82, 19.58, and 42.40 for the undoped form and M, M@ZnO, 5M@ZnO-BG, 10M@ZnO-BG, and 20M@ZnO-BG NP-doped forms of the HPTS-based thin films, respectively. The response and recovery times of the HPTS-based sensing slide along with 20M@ZnO-BG NPs have been measured as 44 and 276 s, respectively. The γ-Fe(2)O(3)/ZnO-containing BG particle-doped HPTS composites can be used as a promising sensor agent in the detection of CO(2) gas in various fields such as environmental monitoring, medical diagnostics, and industrial processes.
format Online
Article
Text
id pubmed-10620782
institution National Center for Biotechnology Information
language English
publishDate 2023
publisher American Chemical Society
record_format MEDLINE/PubMed
spelling pubmed-106207822023-11-03 Effect on Improving CO(2) Sensor Properties: Combination of HPTS and γ-Fe(2)O(3)@ZnO Bioactive Glass Oguzlar, Sibel Zeyrek Ongun, Merve Deliormanlı, Aylin M. ACS Omega [Image: see text] 8-Hydroxypyrene-1,3,6-trisulfonic acid (HPTS) dye, a fluorescent dye often used as a pH indicator, is embedded within the bioactive glass matrix and undergoes changes in its fluorescent properties when exposed to carbon dioxide (CO(2)). The aim of the current study is to investigate the use of bioactive glass (BG) particles containing γ-Fe(2)O(3)@ZnO to enhance the CO(2) sensitivity of HPTS. X-ray diffraction, Fourier transform infrared, scanning electron microscopy, and photoluminescence spectroscopies were used to characterize the sol–gel synthesized powders. The sensing slides were prepared in the form of a thin film by immobilizing the fluorescent dye and γ-Fe(2)O(3)@ZnO-based additives into the poly(methyl methacrylate) matrix. The addition of γ-Fe(2)O(3)@ZnO nanoparticles with bioactive glass additives to the HPTS improves the performance characteristics of the sensor, including the linear response range, relative signal variation, and sensitivity. Meanwhile, the CO(2) sensitivities were measured as 10.22, 7.73, 16.56, 17.82, 19.58, and 42.40 for the undoped form and M, M@ZnO, 5M@ZnO-BG, 10M@ZnO-BG, and 20M@ZnO-BG NP-doped forms of the HPTS-based thin films, respectively. The response and recovery times of the HPTS-based sensing slide along with 20M@ZnO-BG NPs have been measured as 44 and 276 s, respectively. The γ-Fe(2)O(3)/ZnO-containing BG particle-doped HPTS composites can be used as a promising sensor agent in the detection of CO(2) gas in various fields such as environmental monitoring, medical diagnostics, and industrial processes. American Chemical Society 2023-10-16 /pmc/articles/PMC10620782/ /pubmed/37929109 http://dx.doi.org/10.1021/acsomega.3c05361 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Oguzlar, Sibel
Zeyrek Ongun, Merve
Deliormanlı, Aylin M.
Effect on Improving CO(2) Sensor Properties: Combination of HPTS and γ-Fe(2)O(3)@ZnO Bioactive Glass
title Effect on Improving CO(2) Sensor Properties: Combination of HPTS and γ-Fe(2)O(3)@ZnO Bioactive Glass
title_full Effect on Improving CO(2) Sensor Properties: Combination of HPTS and γ-Fe(2)O(3)@ZnO Bioactive Glass
title_fullStr Effect on Improving CO(2) Sensor Properties: Combination of HPTS and γ-Fe(2)O(3)@ZnO Bioactive Glass
title_full_unstemmed Effect on Improving CO(2) Sensor Properties: Combination of HPTS and γ-Fe(2)O(3)@ZnO Bioactive Glass
title_short Effect on Improving CO(2) Sensor Properties: Combination of HPTS and γ-Fe(2)O(3)@ZnO Bioactive Glass
title_sort effect on improving co(2) sensor properties: combination of hpts and γ-fe(2)o(3)@zno bioactive glass
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10620782/
https://www.ncbi.nlm.nih.gov/pubmed/37929109
http://dx.doi.org/10.1021/acsomega.3c05361
work_keys_str_mv AT oguzlarsibel effectonimprovingco2sensorpropertiescombinationofhptsandgfe2o3znobioactiveglass
AT zeyrekongunmerve effectonimprovingco2sensorpropertiescombinationofhptsandgfe2o3znobioactiveglass
AT deliormanlıaylinm effectonimprovingco2sensorpropertiescombinationofhptsandgfe2o3znobioactiveglass