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An advanced PdNPs@MoS(2) nanocomposite for efficient oxygen evolution reaction in alkaline media

In response to the increasing availability of hydrogen energy and renewable energy sources, molybdenum disulfide (MoS(2))-based electrocatalysts are becoming increasingly important for efficient electrochemical water splitting. This study involves the incorporation of palladium nanoparticles (PdNPs)...

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Detalles Bibliográficos
Autores principales: Aftab, Umair, Solangi, Muhammad Yameen, Tahira, Aneela, Hanan, Abdul, Abro, Muhammad Ishaq, Karsy, Amal, Dawi, Elmuez, Bhatti, Muhammad Ali, Alshammari, Riyadh H., Nafady, Ayman, Gradone, Alessandro, Mazzaro, Raffaello, Morandi, Vittorio, Infantes-Molina, Antonia, Ibupoto, Zafar Hussain
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10623383/
https://www.ncbi.nlm.nih.gov/pubmed/37928849
http://dx.doi.org/10.1039/d3ra04738e
Descripción
Sumario:In response to the increasing availability of hydrogen energy and renewable energy sources, molybdenum disulfide (MoS(2))-based electrocatalysts are becoming increasingly important for efficient electrochemical water splitting. This study involves the incorporation of palladium nanoparticles (PdNPs) into hydrothermally grown MoS(2)via a UV light assisted process to afford PdNPs@MoS(2) as an alternative electrocatalyst for efficient energy storage and conversion. Various analytical techniques, including scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and energy dispersive spectroscopy (EDS), were used to investigate the morphology, crystal quality, and chemical composition of the samples. Although PdNPs did not alter the MoS(2) morphology, oxygen evolution reaction (OER) activity was driven at considerable overpotential. When electrochemical water splitting was performed in 1.0 M KOH aqueous solution with PdNPs@MoS(2) (sample-2), an overpotential of 253 mV was observed. Furthermore, OER performance was highly favorable through rapid reaction kinetics and a low Tafel slope of 59 mV dec(−1), as well as high durability and stability. In accordance with the electrochemical results, sample-2 showed also a lower charge transfer resistance, which again provided evidence of OER activity. The enhanced OER activity was attributed to a number of factors, including structural, surface chemical compositions, and synergistic effects between MoS(2) and PdNPs.