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Acceleration and deceleration of chirality inversion speeds in a dynamic helical metallocryptand by alkali metal ion binding
We report that the chirality inversion kinetics of a trinickel(II) cryptand can be controlled by guest recognition in the cryptand cavity. When the guest was absent, the nickel(II) cryptand underwent a dynamic interconversion between the P and M forms in solution, preferring the M form, with a half-...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Association for the Advancement of Science
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10624348/ https://www.ncbi.nlm.nih.gov/pubmed/37922347 http://dx.doi.org/10.1126/sciadv.adj5536 |