Self‐Assembled 2D VS(2)/Ti(3)C(2)T(x) MXene Nanostructures with Ultrafast Kinetics for Superior Electrochemical Sodium‐Ion Storage

Constructing nanostructures with high structural stability and ultrafast electrochemical reaction kinetics as anodes for sodium‐ion batteries (SIBs) is a big challenge. Herein, the robust 2D VS(2)/ Ti(3)C(2)T(x) MXene nanostructures with the strong Ti─S covalent bond synthesized by a one‐pot self‐assembly approach are developed. The strong interfacial interaction renders the material of good structural durability and enhanced reaction kinetics. Meanwhile, the enlarged and few‐layered MXene nanosheets can be easily obtained according to this interaction, providing a conductive network for sufficient electrolyte penetration and rapid charge transfer. As predicted, the VS(2)/MXene nanostructures exhibit an extremely low sodium diffusion barrier confirmed by DFT calculations and small charge transfer impedance evidenced by electrochemical impedance spectroscopy (EIS) analysis. Therefore, the SIBs based on the VS(2)/MXene electrode present first‐class electrochemical performance with the ultrahigh average initial columbic efficiency of 95.08% and excellent sodium‐ion storage capacity of 424.6 mAh g(−1) even at 10 A g(−1). It also shows an outstanding sodium‐ion storage capacity of 514.2 mAh g(−1) at 1 A g(−1) with a capacity retention of nearly 100% within 500 times high‐rate cycling. Such impressive performance demonstrates the successful synthesis strategy and the great potential of interfacial interactions for high‐performance energy storage devices.