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N-(4-Ethoxyphenyl)-3-oxobutanamide
The title compound, C(12)H(15)NO(3), crystallizes with Z′ = 2 in space group Pca2(1) with the two independent molecules having almost the same conformation, differing mostly at the end of the butanamide chain. A local inversion center near 1/8, 3/4, z relates the two molecules, as is common for st...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10626611/ https://www.ncbi.nlm.nih.gov/pubmed/37937129 http://dx.doi.org/10.1107/S2414314623005655 |
Sumario: | The title compound, C(12)H(15)NO(3), crystallizes with Z′ = 2 in space group Pca2(1) with the two independent molecules having almost the same conformation, differing mostly at the end of the butanamide chain. A local inversion center near 1/8, 3/4, z relates the two molecules, as is common for structures in this space group with Z′ = 2. The molecule crystallizes as the keto tautomer, and the β-diketone moieties are twisted out of planarity, with O—C⋯C—O pseudo torsion angles of −74.4 (5) and −83.9 (5)°. The N—H group of each independent molecule donates an intermolecular hydrogen bond to an amide carbonyl oxygen atom by positive or negative translations along the b axis, thus forming antiparallel chains propagating in the [010] direction. [Image: see text] |
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