4-Methyl-2-(2-methyl­anilino)benzoic acid

The title compound, C(15)H(15)NO(2), was obtained by the reaction of 2-chloro-4-methyl-benzoic acid and o-toluidine using 2-eth­oxy­ethanol as solvent. Crystals of the title compounds were obtained from crystallization in acetone. The mol­ecule in the crystal is twisted with a dihedral angle between...

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Detalles Bibliográficos
Autores principales: Liu, Chenxin, Long, Sihui
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10626613/
https://www.ncbi.nlm.nih.gov/pubmed/37937126
http://dx.doi.org/10.1107/S2414314623005990
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author Liu, Chenxin
Long, Sihui
author_facet Liu, Chenxin
Long, Sihui
author_sort Liu, Chenxin
collection PubMed
description The title compound, C(15)H(15)NO(2), was obtained by the reaction of 2-chloro-4-methyl-benzoic acid and o-toluidine using 2-eth­oxy­ethanol as solvent. Crystals of the title compounds were obtained from crystallization in acetone. The mol­ecule in the crystal is twisted with a dihedral angle between the aromatic rings of 50.86 (5)°. In the crystal structure, the mol­ecules associate to form acid–acid hydrogen-bonded dimers linked by pairwise O—H⋯O hydrogen bonds. [Image: see text]
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spelling pubmed-106266132023-11-07 4-Methyl-2-(2-methyl­anilino)benzoic acid Liu, Chenxin Long, Sihui IUCrdata Data Reports The title compound, C(15)H(15)NO(2), was obtained by the reaction of 2-chloro-4-methyl-benzoic acid and o-toluidine using 2-eth­oxy­ethanol as solvent. Crystals of the title compounds were obtained from crystallization in acetone. The mol­ecule in the crystal is twisted with a dihedral angle between the aromatic rings of 50.86 (5)°. In the crystal structure, the mol­ecules associate to form acid–acid hydrogen-bonded dimers linked by pairwise O—H⋯O hydrogen bonds. [Image: see text] International Union of Crystallography 2023-07-14 /pmc/articles/PMC10626613/ /pubmed/37937126 http://dx.doi.org/10.1107/S2414314623005990 Text en © Liu and Long 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Liu, Chenxin
Long, Sihui
4-Methyl-2-(2-methyl­anilino)benzoic acid
title 4-Methyl-2-(2-methyl­anilino)benzoic acid
title_full 4-Methyl-2-(2-methyl­anilino)benzoic acid
title_fullStr 4-Methyl-2-(2-methyl­anilino)benzoic acid
title_full_unstemmed 4-Methyl-2-(2-methyl­anilino)benzoic acid
title_short 4-Methyl-2-(2-methyl­anilino)benzoic acid
title_sort 4-methyl-2-(2-methyl­anilino)benzoic acid
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10626613/
https://www.ncbi.nlm.nih.gov/pubmed/37937126
http://dx.doi.org/10.1107/S2414314623005990
work_keys_str_mv AT liuchenxin 4methyl22methylanilinobenzoicacid
AT longsihui 4methyl22methylanilinobenzoicacid

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