H-type Ce(2)[Si(2)O(7)]

The title compound, dicerium(III) oxidodisilicate, Ce(2)[Si(2)O(7)], was obtained as a by-product in its H-type structure after attempts to synthesize CeSb(2)O(4)Cl from fused silica ampoules. It crystallizes isotypically with H-La(2)[Si(2)O(7)]. The four crystallographically distinct Ce(III) cation...

Descripción completa

Detalles Bibliográficos
Autores principales: Locke, Ralf Jules Christian, Weis, Maria, Schleid, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10626614/
https://www.ncbi.nlm.nih.gov/pubmed/37937134
http://dx.doi.org/10.1107/S2414314623005916
_version_ 1785131372723044352
author Locke, Ralf Jules Christian
Weis, Maria
Schleid, Thomas
author_facet Locke, Ralf Jules Christian
Weis, Maria
Schleid, Thomas
author_sort Locke, Ralf Jules Christian
collection PubMed
description The title compound, dicerium(III) oxidodisilicate, Ce(2)[Si(2)O(7)], was obtained as a by-product in its H-type structure after attempts to synthesize CeSb(2)O(4)Cl from fused silica ampoules. It crystallizes isotypically with H-La(2)[Si(2)O(7)]. The four crystallographically distinct Ce(III) cations form distorted square anti­prisms, capped square anti­prisms, and bicapped square anti­prisms as coordination polyhedra consisting of oxygen atoms. Four crystallographically different silicon atoms recruit the centers of two different isolated [Si(2)O(7)](6–) units. [Image: see text]
format Online
Article
Text
id pubmed-10626614
institution National Center for Biotechnology Information
language English
publishDate 2023
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-106266142023-11-07 H-type Ce(2)[Si(2)O(7)] Locke, Ralf Jules Christian Weis, Maria Schleid, Thomas IUCrdata Data Reports The title compound, dicerium(III) oxidodisilicate, Ce(2)[Si(2)O(7)], was obtained as a by-product in its H-type structure after attempts to synthesize CeSb(2)O(4)Cl from fused silica ampoules. It crystallizes isotypically with H-La(2)[Si(2)O(7)]. The four crystallographically distinct Ce(III) cations form distorted square anti­prisms, capped square anti­prisms, and bicapped square anti­prisms as coordination polyhedra consisting of oxygen atoms. Four crystallographically different silicon atoms recruit the centers of two different isolated [Si(2)O(7)](6–) units. [Image: see text] International Union of Crystallography 2023-07-07 /pmc/articles/PMC10626614/ /pubmed/37937134 http://dx.doi.org/10.1107/S2414314623005916 Text en © Locke et al. 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Locke, Ralf Jules Christian
Weis, Maria
Schleid, Thomas
H-type Ce(2)[Si(2)O(7)]
title H-type Ce(2)[Si(2)O(7)]
title_full H-type Ce(2)[Si(2)O(7)]
title_fullStr H-type Ce(2)[Si(2)O(7)]
title_full_unstemmed H-type Ce(2)[Si(2)O(7)]
title_short H-type Ce(2)[Si(2)O(7)]
title_sort h-type ce(2)[si(2)o(7)]
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10626614/
https://www.ncbi.nlm.nih.gov/pubmed/37937134
http://dx.doi.org/10.1107/S2414314623005916
work_keys_str_mv AT lockeralfjuleschristian htypece2si2o7
AT weismaria htypece2si2o7
AT schleidthomas htypece2si2o7

Ejemplares similares