Aqua­{μ-1,4-bis­[(1,4,7,10-tetra­aza­cyclo­dodecan-1-yl)meth­yl]benzene}(nitrato-κO)dicopper(II) tris­(nitrate) trihydrate

In the title dinuclear Cu(II) complex, [Cu(2)(NO(3))(C(24)H(46)N(8))(H(2)O)](NO(3))(3)·3H(2)O, the two Cu(II) mol­ecules both have a square-pyramidal geometry, but the ligands in the axial positions are different: a water mol­ecule and a nitrate ion. All nitrate ions, water mol­ecules, and N—H group...

Descripción completa

Detalles Bibliográficos
Autores principales: Ichimaru, Yoshimi, Kato, Koichi, Sugiura, Kirara, Ogawa, Sarina, Jin, Wanchun, Kurihara, Masaaki, Yamaguchi, Yoshihiro, Imai, Masanori, Kurosaki, Hiromasa
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10626620/
https://www.ncbi.nlm.nih.gov/pubmed/37936873
http://dx.doi.org/10.1107/S2414314623004625
Descripción
Sumario:In the title dinuclear Cu(II) complex, [Cu(2)(NO(3))(C(24)H(46)N(8))(H(2)O)](NO(3))(3)·3H(2)O, the two Cu(II) mol­ecules both have a square-pyramidal geometry, but the ligands in the axial positions are different: a water mol­ecule and a nitrate ion. All nitrate ions, water mol­ecules, and N—H groups are involved in an inter­molecular hydrogen-bond network. [Image: see text]

Ejemplares similares