Aqua­{μ-1,4-bis­[(1,4,7,10-tetra­aza­cyclo­dodecan-1-yl)meth­yl]benzene}(nitrato-κO)dicopper(II) tris­(nitrate) trihydrate

In the title dinuclear Cu(II) complex, [Cu(2)(NO(3))(C(24)H(46)N(8))(H(2)O)](NO(3))(3)·3H(2)O, the two Cu(II) mol­ecules both have a square-pyramidal geometry, but the ligands in the axial positions are different: a water mol­ecule and a nitrate ion. All nitrate ions, water mol­ecules, and N—H group...

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Autores principales: Ichimaru, Yoshimi, Kato, Koichi, Sugiura, Kirara, Ogawa, Sarina, Jin, Wanchun, Kurihara, Masaaki, Yamaguchi, Yoshihiro, Imai, Masanori, Kurosaki, Hiromasa
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10626620/
https://www.ncbi.nlm.nih.gov/pubmed/37936873
http://dx.doi.org/10.1107/S2414314623004625
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author Ichimaru, Yoshimi
Kato, Koichi
Sugiura, Kirara
Ogawa, Sarina
Jin, Wanchun
Kurihara, Masaaki
Yamaguchi, Yoshihiro
Imai, Masanori
Kurosaki, Hiromasa
author_facet Ichimaru, Yoshimi
Kato, Koichi
Sugiura, Kirara
Ogawa, Sarina
Jin, Wanchun
Kurihara, Masaaki
Yamaguchi, Yoshihiro
Imai, Masanori
Kurosaki, Hiromasa
author_sort Ichimaru, Yoshimi
collection PubMed
description In the title dinuclear Cu(II) complex, [Cu(2)(NO(3))(C(24)H(46)N(8))(H(2)O)](NO(3))(3)·3H(2)O, the two Cu(II) mol­ecules both have a square-pyramidal geometry, but the ligands in the axial positions are different: a water mol­ecule and a nitrate ion. All nitrate ions, water mol­ecules, and N—H groups are involved in an inter­molecular hydrogen-bond network. [Image: see text]
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spelling pubmed-106266202023-11-07 Aqua­{μ-1,4-bis­[(1,4,7,10-tetra­aza­cyclo­dodecan-1-yl)meth­yl]benzene}(nitrato-κO)dicopper(II) tris­(nitrate) trihydrate Ichimaru, Yoshimi Kato, Koichi Sugiura, Kirara Ogawa, Sarina Jin, Wanchun Kurihara, Masaaki Yamaguchi, Yoshihiro Imai, Masanori Kurosaki, Hiromasa IUCrdata Data Reports In the title dinuclear Cu(II) complex, [Cu(2)(NO(3))(C(24)H(46)N(8))(H(2)O)](NO(3))(3)·3H(2)O, the two Cu(II) mol­ecules both have a square-pyramidal geometry, but the ligands in the axial positions are different: a water mol­ecule and a nitrate ion. All nitrate ions, water mol­ecules, and N—H groups are involved in an inter­molecular hydrogen-bond network. [Image: see text] International Union of Crystallography 2023-06-02 /pmc/articles/PMC10626620/ /pubmed/37936873 http://dx.doi.org/10.1107/S2414314623004625 Text en © Ichimaru et al. 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Ichimaru, Yoshimi
Kato, Koichi
Sugiura, Kirara
Ogawa, Sarina
Jin, Wanchun
Kurihara, Masaaki
Yamaguchi, Yoshihiro
Imai, Masanori
Kurosaki, Hiromasa
Aqua­{μ-1,4-bis­[(1,4,7,10-tetra­aza­cyclo­dodecan-1-yl)meth­yl]benzene}(nitrato-κO)dicopper(II) tris­(nitrate) trihydrate
title Aqua­{μ-1,4-bis­[(1,4,7,10-tetra­aza­cyclo­dodecan-1-yl)meth­yl]benzene}(nitrato-κO)dicopper(II) tris­(nitrate) trihydrate
title_full Aqua­{μ-1,4-bis­[(1,4,7,10-tetra­aza­cyclo­dodecan-1-yl)meth­yl]benzene}(nitrato-κO)dicopper(II) tris­(nitrate) trihydrate
title_fullStr Aqua­{μ-1,4-bis­[(1,4,7,10-tetra­aza­cyclo­dodecan-1-yl)meth­yl]benzene}(nitrato-κO)dicopper(II) tris­(nitrate) trihydrate
title_full_unstemmed Aqua­{μ-1,4-bis­[(1,4,7,10-tetra­aza­cyclo­dodecan-1-yl)meth­yl]benzene}(nitrato-κO)dicopper(II) tris­(nitrate) trihydrate
title_short Aqua­{μ-1,4-bis­[(1,4,7,10-tetra­aza­cyclo­dodecan-1-yl)meth­yl]benzene}(nitrato-κO)dicopper(II) tris­(nitrate) trihydrate
title_sort aqua­{μ-1,4-bis­[(1,4,7,10-tetra­aza­cyclo­dodecan-1-yl)meth­yl]benzene}(nitrato-κo)dicopper(ii) tris­(nitrate) trihydrate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10626620/
https://www.ncbi.nlm.nih.gov/pubmed/37936873
http://dx.doi.org/10.1107/S2414314623004625
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