Cargando…

Poly[bis­(O-ethyl­hydroxy­laminium) [di-μ-chlorido-di­chlorido­cadmate(II)]]

The title compound, {(CH(3)CH(2)ONH(3))(2)[CdCl(4)]}( n ), consists of bilayers of organic CH(3)CH(2)ONH(3) (+) cations and infinite [CdCl(4)]( n ) (2n−) inorganic layers. It can be described as an organic–inorganic hybrid layered perovskite. In the crystal structure, the Cd(II) cation is situated a...

Descripción completa

Detalles Bibliográficos
Autores principales: Tong, Yu-Qiao, Lei, Zi-Qiong, Huang, Bo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10626843/
https://www.ncbi.nlm.nih.gov/pubmed/37936586
http://dx.doi.org/10.1107/S2414314623008982
_version_ 1785131425029160960
author Tong, Yu-Qiao
Lei, Zi-Qiong
Huang, Bo
author_facet Tong, Yu-Qiao
Lei, Zi-Qiong
Huang, Bo
author_sort Tong, Yu-Qiao
collection PubMed
description The title compound, {(CH(3)CH(2)ONH(3))(2)[CdCl(4)]}( n ), consists of bilayers of organic CH(3)CH(2)ONH(3) (+) cations and infinite [CdCl(4)]( n ) (2n−) inorganic layers. It can be described as an organic–inorganic hybrid layered perovskite. In the crystal structure, the Cd(II) cation is situated at an inversion center and is coordinated by six chloride ions, forming a slightly distorted octa­hedral coordination polyhedron. By corner-sharing of the [CdCl(6)] octa­hedra, infinite [CdCl(4)]( n ) (2n−) inorganic layers are formed, extending parallel to (100). The inorganic layers alternate with bilayers of CH(3)CH(2)ONH(3) (+) cations, whereby the connection of the cationic and anionic layers is achieved through N—H⋯Cl hydrogen bonds and Coulombic inter­actions. [Image: see text]
format Online
Article
Text
id pubmed-10626843
institution National Center for Biotechnology Information
language English
publishDate 2023
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-106268432023-11-07 Poly[bis­(O-ethyl­hydroxy­laminium) [di-μ-chlorido-di­chlorido­cadmate(II)]] Tong, Yu-Qiao Lei, Zi-Qiong Huang, Bo IUCrdata Data Reports The title compound, {(CH(3)CH(2)ONH(3))(2)[CdCl(4)]}( n ), consists of bilayers of organic CH(3)CH(2)ONH(3) (+) cations and infinite [CdCl(4)]( n ) (2n−) inorganic layers. It can be described as an organic–inorganic hybrid layered perovskite. In the crystal structure, the Cd(II) cation is situated at an inversion center and is coordinated by six chloride ions, forming a slightly distorted octa­hedral coordination polyhedron. By corner-sharing of the [CdCl(6)] octa­hedra, infinite [CdCl(4)]( n ) (2n−) inorganic layers are formed, extending parallel to (100). The inorganic layers alternate with bilayers of CH(3)CH(2)ONH(3) (+) cations, whereby the connection of the cationic and anionic layers is achieved through N—H⋯Cl hydrogen bonds and Coulombic inter­actions. [Image: see text] International Union of Crystallography 2023-10-19 /pmc/articles/PMC10626843/ /pubmed/37936586 http://dx.doi.org/10.1107/S2414314623008982 Text en © Tong et al. 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Tong, Yu-Qiao
Lei, Zi-Qiong
Huang, Bo
Poly[bis­(O-ethyl­hydroxy­laminium) [di-μ-chlorido-di­chlorido­cadmate(II)]]
title Poly[bis­(O-ethyl­hydroxy­laminium) [di-μ-chlorido-di­chlorido­cadmate(II)]]
title_full Poly[bis­(O-ethyl­hydroxy­laminium) [di-μ-chlorido-di­chlorido­cadmate(II)]]
title_fullStr Poly[bis­(O-ethyl­hydroxy­laminium) [di-μ-chlorido-di­chlorido­cadmate(II)]]
title_full_unstemmed Poly[bis­(O-ethyl­hydroxy­laminium) [di-μ-chlorido-di­chlorido­cadmate(II)]]
title_short Poly[bis­(O-ethyl­hydroxy­laminium) [di-μ-chlorido-di­chlorido­cadmate(II)]]
title_sort poly[bis­(o-ethyl­hydroxy­laminium) [di-μ-chlorido-di­chlorido­cadmate(ii)]]
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10626843/
https://www.ncbi.nlm.nih.gov/pubmed/37936586
http://dx.doi.org/10.1107/S2414314623008982
work_keys_str_mv AT tongyuqiao polybisoethylhydroxylaminiumdimchloridodichloridocadmateii
AT leiziqiong polybisoethylhydroxylaminiumdimchloridodichloridocadmateii
AT huangbo polybisoethylhydroxylaminiumdimchloridodichloridocadmateii