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Poly[[(μ(3)-adamantane-1,3-di­acetato)[μ-N-(pyridin-3-yl)isonicotinamide]­nickel(II)] monohydrate], a layered coordination polymer with triangular (3,6) topology

The title compound, {[Ni(C(14)H(18)O(4))(C(11)H(9)N(3)O)]·H(2)O}( n ), contains octa­hedrally coordinated Ni(II) ions ligated by 1,3-adamantanedi­acetato (ada) ligands and N-(pyridin-3-yl)isonicotinamide (3-pina) ligands, to form coordination polymer layers with a triangular (3,6) grid topology base...

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Detalles Bibliográficos
Autores principales: Travis, Jamelah Z., LaDuca, Robert L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10626845/
https://www.ncbi.nlm.nih.gov/pubmed/37936594
http://dx.doi.org/10.1107/S2414314623008696
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author Travis, Jamelah Z.
LaDuca, Robert L.
author_facet Travis, Jamelah Z.
LaDuca, Robert L.
author_sort Travis, Jamelah Z.
collection PubMed
description The title compound, {[Ni(C(14)H(18)O(4))(C(11)H(9)N(3)O)]·H(2)O}( n ), contains octa­hedrally coordinated Ni(II) ions ligated by 1,3-adamantanedi­acetato (ada) ligands and N-(pyridin-3-yl)isonicotinamide (3-pina) ligands, to form coordination polymer layers with a triangular (3,6) grid topology based on [Ni(2)(OCO)(2)] dimeric units. The diperiodic layer motifs stack in an ABAB pattern mediated by C—H⋯O supra­molecular inter­actions between ada ligands and water mol­ecules of crystallization to form the full triperiodic crystal structure of the title compound. [Image: see text]
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spelling pubmed-106268452023-11-07 Poly[[(μ(3)-adamantane-1,3-di­acetato)[μ-N-(pyridin-3-yl)isonicotinamide]­nickel(II)] monohydrate], a layered coordination polymer with triangular (3,6) topology Travis, Jamelah Z. LaDuca, Robert L. IUCrdata Data Reports The title compound, {[Ni(C(14)H(18)O(4))(C(11)H(9)N(3)O)]·H(2)O}( n ), contains octa­hedrally coordinated Ni(II) ions ligated by 1,3-adamantanedi­acetato (ada) ligands and N-(pyridin-3-yl)isonicotinamide (3-pina) ligands, to form coordination polymer layers with a triangular (3,6) grid topology based on [Ni(2)(OCO)(2)] dimeric units. The diperiodic layer motifs stack in an ABAB pattern mediated by C—H⋯O supra­molecular inter­actions between ada ligands and water mol­ecules of crystallization to form the full triperiodic crystal structure of the title compound. [Image: see text] International Union of Crystallography 2023-10-05 /pmc/articles/PMC10626845/ /pubmed/37936594 http://dx.doi.org/10.1107/S2414314623008696 Text en © Travis and LaDuca 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Travis, Jamelah Z.
LaDuca, Robert L.
Poly[[(μ(3)-adamantane-1,3-di­acetato)[μ-N-(pyridin-3-yl)isonicotinamide]­nickel(II)] monohydrate], a layered coordination polymer with triangular (3,6) topology
title Poly[[(μ(3)-adamantane-1,3-di­acetato)[μ-N-(pyridin-3-yl)isonicotinamide]­nickel(II)] monohydrate], a layered coordination polymer with triangular (3,6) topology
title_full Poly[[(μ(3)-adamantane-1,3-di­acetato)[μ-N-(pyridin-3-yl)isonicotinamide]­nickel(II)] monohydrate], a layered coordination polymer with triangular (3,6) topology
title_fullStr Poly[[(μ(3)-adamantane-1,3-di­acetato)[μ-N-(pyridin-3-yl)isonicotinamide]­nickel(II)] monohydrate], a layered coordination polymer with triangular (3,6) topology
title_full_unstemmed Poly[[(μ(3)-adamantane-1,3-di­acetato)[μ-N-(pyridin-3-yl)isonicotinamide]­nickel(II)] monohydrate], a layered coordination polymer with triangular (3,6) topology
title_short Poly[[(μ(3)-adamantane-1,3-di­acetato)[μ-N-(pyridin-3-yl)isonicotinamide]­nickel(II)] monohydrate], a layered coordination polymer with triangular (3,6) topology
title_sort poly[[(μ(3)-adamantane-1,3-di­acetato)[μ-n-(pyridin-3-yl)isonicotinamide]­nickel(ii)] monohydrate], a layered coordination polymer with triangular (3,6) topology
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10626845/
https://www.ncbi.nlm.nih.gov/pubmed/37936594
http://dx.doi.org/10.1107/S2414314623008696
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