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Poly[[(μ(3)-adamantane-1,3-diacetato)[μ-N-(pyridin-3-yl)isonicotinamide]nickel(II)] monohydrate], a layered coordination polymer with triangular (3,6) topology
The title compound, {[Ni(C(14)H(18)O(4))(C(11)H(9)N(3)O)]·H(2)O}( n ), contains octahedrally coordinated Ni(II) ions ligated by 1,3-adamantanediacetato (ada) ligands and N-(pyridin-3-yl)isonicotinamide (3-pina) ligands, to form coordination polymer layers with a triangular (3,6) grid topology base...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10626845/ https://www.ncbi.nlm.nih.gov/pubmed/37936594 http://dx.doi.org/10.1107/S2414314623008696 |
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author | Travis, Jamelah Z. LaDuca, Robert L. |
author_facet | Travis, Jamelah Z. LaDuca, Robert L. |
author_sort | Travis, Jamelah Z. |
collection | PubMed |
description | The title compound, {[Ni(C(14)H(18)O(4))(C(11)H(9)N(3)O)]·H(2)O}( n ), contains octahedrally coordinated Ni(II) ions ligated by 1,3-adamantanediacetato (ada) ligands and N-(pyridin-3-yl)isonicotinamide (3-pina) ligands, to form coordination polymer layers with a triangular (3,6) grid topology based on [Ni(2)(OCO)(2)] dimeric units. The diperiodic layer motifs stack in an ABAB pattern mediated by C—H⋯O supramolecular interactions between ada ligands and water molecules of crystallization to form the full triperiodic crystal structure of the title compound. [Image: see text] |
format | Online Article Text |
id | pubmed-10626845 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-106268452023-11-07 Poly[[(μ(3)-adamantane-1,3-diacetato)[μ-N-(pyridin-3-yl)isonicotinamide]nickel(II)] monohydrate], a layered coordination polymer with triangular (3,6) topology Travis, Jamelah Z. LaDuca, Robert L. IUCrdata Data Reports The title compound, {[Ni(C(14)H(18)O(4))(C(11)H(9)N(3)O)]·H(2)O}( n ), contains octahedrally coordinated Ni(II) ions ligated by 1,3-adamantanediacetato (ada) ligands and N-(pyridin-3-yl)isonicotinamide (3-pina) ligands, to form coordination polymer layers with a triangular (3,6) grid topology based on [Ni(2)(OCO)(2)] dimeric units. The diperiodic layer motifs stack in an ABAB pattern mediated by C—H⋯O supramolecular interactions between ada ligands and water molecules of crystallization to form the full triperiodic crystal structure of the title compound. [Image: see text] International Union of Crystallography 2023-10-05 /pmc/articles/PMC10626845/ /pubmed/37936594 http://dx.doi.org/10.1107/S2414314623008696 Text en © Travis and LaDuca 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Travis, Jamelah Z. LaDuca, Robert L. Poly[[(μ(3)-adamantane-1,3-diacetato)[μ-N-(pyridin-3-yl)isonicotinamide]nickel(II)] monohydrate], a layered coordination polymer with triangular (3,6) topology |
title | Poly[[(μ(3)-adamantane-1,3-diacetato)[μ-N-(pyridin-3-yl)isonicotinamide]nickel(II)] monohydrate], a layered coordination polymer with triangular (3,6) topology |
title_full | Poly[[(μ(3)-adamantane-1,3-diacetato)[μ-N-(pyridin-3-yl)isonicotinamide]nickel(II)] monohydrate], a layered coordination polymer with triangular (3,6) topology |
title_fullStr | Poly[[(μ(3)-adamantane-1,3-diacetato)[μ-N-(pyridin-3-yl)isonicotinamide]nickel(II)] monohydrate], a layered coordination polymer with triangular (3,6) topology |
title_full_unstemmed | Poly[[(μ(3)-adamantane-1,3-diacetato)[μ-N-(pyridin-3-yl)isonicotinamide]nickel(II)] monohydrate], a layered coordination polymer with triangular (3,6) topology |
title_short | Poly[[(μ(3)-adamantane-1,3-diacetato)[μ-N-(pyridin-3-yl)isonicotinamide]nickel(II)] monohydrate], a layered coordination polymer with triangular (3,6) topology |
title_sort | poly[[(μ(3)-adamantane-1,3-diacetato)[μ-n-(pyridin-3-yl)isonicotinamide]nickel(ii)] monohydrate], a layered coordination polymer with triangular (3,6) topology |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10626845/ https://www.ncbi.nlm.nih.gov/pubmed/37936594 http://dx.doi.org/10.1107/S2414314623008696 |
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