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Bis(diisobutylammonium) tetrachloridobis[3-(trifluoromethyl)phenyl]stannate
The asymmetric unit in the title salt, (C(8)H(20)N)(2)[SnCl(4)(C(7)H(4)Cl(2)F(3))(2)], features a di-isobutylammonium cation in a general position and a diorganotin tetrachloride dianion, i.e. tetrachloridobis(3-trifuoromethylphenyl)stannate(IV), located on a centre of inversion; the Sn(IV)...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10626849/ https://www.ncbi.nlm.nih.gov/pubmed/37936588 http://dx.doi.org/10.1107/S2414314623009136 |
Sumario: | The asymmetric unit in the title salt, (C(8)H(20)N)(2)[SnCl(4)(C(7)H(4)Cl(2)F(3))(2)], features a di-isobutylammonium cation in a general position and a diorganotin tetrachloride dianion, i.e. tetrachloridobis(3-trifuoromethylphenyl)stannate(IV), located on a centre of inversion; the Sn(IV) atom is octahedrally coordinated. In the crystal, charge-assisted N(+)—H⋯Cl hydrogen bonds along with C—H⋯F contacts occur within supramolecular layers that interdigitate along the a-axis direction. [Image: see text] |
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