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Bis(diiso­butyl­ammonium) tetra­chlorido­bis­[3-(tri­fluorometh­yl)phen­yl]stannate

The asymmetric unit in the title salt, (C(8)H(20)N)(2)[SnCl(4)(C(7)H(4)Cl(2)F(3))(2)], features a di-isobutyl­ammonium cation in a general position and a diorganotin tetra­chloride dianion, i.e. tetra­chlorido­bis­(3-trifuoro­methyl­phen­yl)stannate(IV), located on a centre of inversion; the Sn(IV)...

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Detalles Bibliográficos
Autores principales: Song, Xueqing, Li, William
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10626849/
https://www.ncbi.nlm.nih.gov/pubmed/37936588
http://dx.doi.org/10.1107/S2414314623009136
Descripción
Sumario:The asymmetric unit in the title salt, (C(8)H(20)N)(2)[SnCl(4)(C(7)H(4)Cl(2)F(3))(2)], features a di-isobutyl­ammonium cation in a general position and a diorganotin tetra­chloride dianion, i.e. tetra­chlorido­bis­(3-trifuoro­methyl­phen­yl)stannate(IV), located on a centre of inversion; the Sn(IV) atom is octa­hedrally coordinated. In the crystal, charge-assisted N(+)—H⋯Cl hydrogen bonds along with C—H⋯F contacts occur within supra­molecular layers that inter­digitate along the a-axis direction. [Image: see text]