Bis(diiso­butyl­ammonium) tetra­chlorido­bis­[3-(tri­fluorometh­yl)phen­yl]stannate

The asymmetric unit in the title salt, (C(8)H(20)N)(2)[SnCl(4)(C(7)H(4)Cl(2)F(3))(2)], features a di-isobutyl­ammonium cation in a general position and a diorganotin tetra­chloride dianion, i.e. tetra­chlorido­bis­(3-trifuoro­methyl­phen­yl)stannate(IV), located on a centre of inversion; the Sn(IV)...

Descripción completa

Detalles Bibliográficos
Autores principales: Song, Xueqing, Li, William
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10626849/
https://www.ncbi.nlm.nih.gov/pubmed/37936588
http://dx.doi.org/10.1107/S2414314623009136
_version_ 1785131426432155648
author Song, Xueqing
Li, William
author_facet Song, Xueqing
Li, William
author_sort Song, Xueqing
collection PubMed
description The asymmetric unit in the title salt, (C(8)H(20)N)(2)[SnCl(4)(C(7)H(4)Cl(2)F(3))(2)], features a di-isobutyl­ammonium cation in a general position and a diorganotin tetra­chloride dianion, i.e. tetra­chlorido­bis­(3-trifuoro­methyl­phen­yl)stannate(IV), located on a centre of inversion; the Sn(IV) atom is octa­hedrally coordinated. In the crystal, charge-assisted N(+)—H⋯Cl hydrogen bonds along with C—H⋯F contacts occur within supra­molecular layers that inter­digitate along the a-axis direction. [Image: see text]
format Online
Article
Text
id pubmed-10626849
institution National Center for Biotechnology Information
language English
publishDate 2023
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-106268492023-11-07 Bis(diiso­butyl­ammonium) tetra­chlorido­bis­[3-(tri­fluorometh­yl)phen­yl]stannate Song, Xueqing Li, William IUCrdata Data Reports The asymmetric unit in the title salt, (C(8)H(20)N)(2)[SnCl(4)(C(7)H(4)Cl(2)F(3))(2)], features a di-isobutyl­ammonium cation in a general position and a diorganotin tetra­chloride dianion, i.e. tetra­chlorido­bis­(3-trifuoro­methyl­phen­yl)stannate(IV), located on a centre of inversion; the Sn(IV) atom is octa­hedrally coordinated. In the crystal, charge-assisted N(+)—H⋯Cl hydrogen bonds along with C—H⋯F contacts occur within supra­molecular layers that inter­digitate along the a-axis direction. [Image: see text] International Union of Crystallography 2023-10-24 /pmc/articles/PMC10626849/ /pubmed/37936588 http://dx.doi.org/10.1107/S2414314623009136 Text en © Song and Li 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Song, Xueqing
Li, William
Bis(diiso­butyl­ammonium) tetra­chlorido­bis­[3-(tri­fluorometh­yl)phen­yl]stannate
title Bis(diiso­butyl­ammonium) tetra­chlorido­bis­[3-(tri­fluorometh­yl)phen­yl]stannate
title_full Bis(diiso­butyl­ammonium) tetra­chlorido­bis­[3-(tri­fluorometh­yl)phen­yl]stannate
title_fullStr Bis(diiso­butyl­ammonium) tetra­chlorido­bis­[3-(tri­fluorometh­yl)phen­yl]stannate
title_full_unstemmed Bis(diiso­butyl­ammonium) tetra­chlorido­bis­[3-(tri­fluorometh­yl)phen­yl]stannate
title_short Bis(diiso­butyl­ammonium) tetra­chlorido­bis­[3-(tri­fluorometh­yl)phen­yl]stannate
title_sort bis(diiso­butyl­ammonium) tetra­chlorido­bis­[3-(tri­fluorometh­yl)phen­yl]stannate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10626849/
https://www.ncbi.nlm.nih.gov/pubmed/37936588
http://dx.doi.org/10.1107/S2414314623009136
work_keys_str_mv AT songxueqing bisdiisobutylammoniumtetrachloridobis3trifluoromethylphenylstannate
AT liwilliam bisdiisobutylammoniumtetrachloridobis3trifluoromethylphenylstannate

Ejemplares similares