Poly[[[μ-1,4-bis­(pyridin-4-ylmeth­yl)piperazine][μ-4-(2-carboxyl­atoeth­yl)benzoato]copper(II)] monohydrate], a coordination polymer with twofold inter­penetrated cds topology networks

The title compound, {[Cu(C(10)H(8)O(4))(C(16)H(20)N(4))]·H(2)O}( n ), contains square-planar coordinated Cu(II) ions linked by 4-(carboxyl­atoeth­yl)benzoato (ceb) and 1,4-bis­(pyridin-4-ylmeth­yl)piperazine (bpmp) ligands into a tri-periodic coordination polymer with twofold inter­penetrating 6(5)8...

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Detalles Bibliográficos
Autores principales: Gaskin, Gabrielle J., LaDuca, Robert L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10626850/
https://www.ncbi.nlm.nih.gov/pubmed/37936595
http://dx.doi.org/10.1107/S2414314623008556
Descripción
Sumario:The title compound, {[Cu(C(10)H(8)O(4))(C(16)H(20)N(4))]·H(2)O}( n ), contains square-planar coordinated Cu(II) ions linked by 4-(carboxyl­atoeth­yl)benzoato (ceb) and 1,4-bis­(pyridin-4-ylmeth­yl)piperazine (bpmp) ligands into a tri-periodic coordination polymer with twofold inter­penetrating 6(5)8 cds topology. Positional crystallographic disorder among the copper atoms, the ethyl­carb­oxy group of the ceb ligands, and the water mol­ecules of crystallization exists in a refined 0.655 (6)/0.345 (6) ratio. [Image: see text]

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