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Poly[[[μ-1,4-bis(pyridin-4-ylmethyl)piperazine][μ-4-(2-carboxylatoethyl)benzoato]copper(II)] monohydrate], a coordination polymer with twofold interpenetrated cds topology networks
The title compound, {[Cu(C(10)H(8)O(4))(C(16)H(20)N(4))]·H(2)O}( n ), contains square-planar coordinated Cu(II) ions linked by 4-(carboxylatoethyl)benzoato (ceb) and 1,4-bis(pyridin-4-ylmethyl)piperazine (bpmp) ligands into a tri-periodic coordination polymer with twofold interpenetrating 6(5)8...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10626850/ https://www.ncbi.nlm.nih.gov/pubmed/37936595 http://dx.doi.org/10.1107/S2414314623008556 |
| _version_ | 1785131426660745216 |
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| author | Gaskin, Gabrielle J. LaDuca, Robert L. |
| author_facet | Gaskin, Gabrielle J. LaDuca, Robert L. |
| author_sort | Gaskin, Gabrielle J. |
| collection | PubMed |
| description | The title compound, {[Cu(C(10)H(8)O(4))(C(16)H(20)N(4))]·H(2)O}( n ), contains square-planar coordinated Cu(II) ions linked by 4-(carboxylatoethyl)benzoato (ceb) and 1,4-bis(pyridin-4-ylmethyl)piperazine (bpmp) ligands into a tri-periodic coordination polymer with twofold interpenetrating 6(5)8 cds topology. Positional crystallographic disorder among the copper atoms, the ethylcarboxy group of the ceb ligands, and the water molecules of crystallization exists in a refined 0.655 (6)/0.345 (6) ratio. [Image: see text] |
| format | Online Article Text |
| id | pubmed-10626850 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2023 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-106268502023-11-07 Poly[[[μ-1,4-bis(pyridin-4-ylmethyl)piperazine][μ-4-(2-carboxylatoethyl)benzoato]copper(II)] monohydrate], a coordination polymer with twofold interpenetrated cds topology networks Gaskin, Gabrielle J. LaDuca, Robert L. IUCrdata Data Reports The title compound, {[Cu(C(10)H(8)O(4))(C(16)H(20)N(4))]·H(2)O}( n ), contains square-planar coordinated Cu(II) ions linked by 4-(carboxylatoethyl)benzoato (ceb) and 1,4-bis(pyridin-4-ylmethyl)piperazine (bpmp) ligands into a tri-periodic coordination polymer with twofold interpenetrating 6(5)8 cds topology. Positional crystallographic disorder among the copper atoms, the ethylcarboxy group of the ceb ligands, and the water molecules of crystallization exists in a refined 0.655 (6)/0.345 (6) ratio. [Image: see text] International Union of Crystallography 2023-10-03 /pmc/articles/PMC10626850/ /pubmed/37936595 http://dx.doi.org/10.1107/S2414314623008556 Text en © Gaskin and LaDuca 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Data Reports Gaskin, Gabrielle J. LaDuca, Robert L. Poly[[[μ-1,4-bis(pyridin-4-ylmethyl)piperazine][μ-4-(2-carboxylatoethyl)benzoato]copper(II)] monohydrate], a coordination polymer with twofold interpenetrated cds topology networks |
| title | Poly[[[μ-1,4-bis(pyridin-4-ylmethyl)piperazine][μ-4-(2-carboxylatoethyl)benzoato]copper(II)] monohydrate], a coordination polymer with twofold interpenetrated cds topology networks |
| title_full | Poly[[[μ-1,4-bis(pyridin-4-ylmethyl)piperazine][μ-4-(2-carboxylatoethyl)benzoato]copper(II)] monohydrate], a coordination polymer with twofold interpenetrated cds topology networks |
| title_fullStr | Poly[[[μ-1,4-bis(pyridin-4-ylmethyl)piperazine][μ-4-(2-carboxylatoethyl)benzoato]copper(II)] monohydrate], a coordination polymer with twofold interpenetrated cds topology networks |
| title_full_unstemmed | Poly[[[μ-1,4-bis(pyridin-4-ylmethyl)piperazine][μ-4-(2-carboxylatoethyl)benzoato]copper(II)] monohydrate], a coordination polymer with twofold interpenetrated cds topology networks |
| title_short | Poly[[[μ-1,4-bis(pyridin-4-ylmethyl)piperazine][μ-4-(2-carboxylatoethyl)benzoato]copper(II)] monohydrate], a coordination polymer with twofold interpenetrated cds topology networks |
| title_sort | poly[[[μ-1,4-bis(pyridin-4-ylmethyl)piperazine][μ-4-(2-carboxylatoethyl)benzoato]copper(ii)] monohydrate], a coordination polymer with twofold interpenetrated cds topology networks |
| topic | Data Reports |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10626850/ https://www.ncbi.nlm.nih.gov/pubmed/37936595 http://dx.doi.org/10.1107/S2414314623008556 |
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