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Crystal structure of (μ-hydrogen di­sulfato)-μ-oxido-bis­[(4,4′-di-tert-butyl-2,2′-bi­pyridine)­oxidovanadium(IV/V)] aceto­nitrile monosolvate

The dinuclear oxidovanadium(IV/V) complex, [V(2)(HS(2)O(8))O(3)(C(18)H(24)N(2))(2)]·CH(3)CN or [V(2)O(2)(μ-O)(μ-H(SO(4))(2))(4,4′-( t )Bubpy)(2)]·CH(3)CN (4,4′-( t )Bubpy = 4,4′-di-tert-butyl-2,2′-bi­pyridine), has crystallographic C (2) symmetry and exhibits a distorted octa­hedral geometry around...

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Detalles Bibliográficos
Autores principales: Kodama, Shintaro, Hashiguchi, Terushi, Nomoto, Akihiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10626945/
https://www.ncbi.nlm.nih.gov/pubmed/37936858
http://dx.doi.org/10.1107/S2056989023009040

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