Crystal structure of 1-(2,6-diiso­propyl­phen­yl)-1H-imidazole

The crystal structure of the title compound, C(15)H(20)N(2) or (Dipp)Im, is reported. At 106 (2) K, the mol­ecule has monoclinic P2(1)/c symmetry with four mol­ecules in the unit cell. The imidazole ring is rotated 80.7 (1)° relative to the phenyl ring. Inter­molecular stabilization primarily result...

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Autores principales: Dudeja, Neil, Arreaga, Briana C., Brannon, Jacob P., Stieber, S. Chantal E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10626946/
https://www.ncbi.nlm.nih.gov/pubmed/37936856
http://dx.doi.org/10.1107/S2056989023009179
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author Dudeja, Neil
Arreaga, Briana C.
Brannon, Jacob P.
Stieber, S. Chantal E.
author_facet Dudeja, Neil
Arreaga, Briana C.
Brannon, Jacob P.
Stieber, S. Chantal E.
author_sort Dudeja, Neil
collection PubMed
description The crystal structure of the title compound, C(15)H(20)N(2) or (Dipp)Im, is reported. At 106 (2) K, the mol­ecule has monoclinic P2(1)/c symmetry with four mol­ecules in the unit cell. The imidazole ring is rotated 80.7 (1)° relative to the phenyl ring. Inter­molecular stabilization primarily results from close contacts between the N atom at the 3-position on the imidazole ring and the C—H bond at the 4-position on the neighboring (Dipp)Im, with ar­yl–aryl distances outside of the accepted distance of 5 Å for π-stacking.
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spelling pubmed-106269462023-11-07 Crystal structure of 1-(2,6-diiso­propyl­phen­yl)-1H-imidazole Dudeja, Neil Arreaga, Briana C. Brannon, Jacob P. Stieber, S. Chantal E. Acta Crystallogr E Crystallogr Commun Research Communications The crystal structure of the title compound, C(15)H(20)N(2) or (Dipp)Im, is reported. At 106 (2) K, the mol­ecule has monoclinic P2(1)/c symmetry with four mol­ecules in the unit cell. The imidazole ring is rotated 80.7 (1)° relative to the phenyl ring. Inter­molecular stabilization primarily results from close contacts between the N atom at the 3-position on the imidazole ring and the C—H bond at the 4-position on the neighboring (Dipp)Im, with ar­yl–aryl distances outside of the accepted distance of 5 Å for π-stacking. International Union of Crystallography 2023-10-26 /pmc/articles/PMC10626946/ /pubmed/37936856 http://dx.doi.org/10.1107/S2056989023009179 Text en © Dudeja et al. 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Dudeja, Neil
Arreaga, Briana C.
Brannon, Jacob P.
Stieber, S. Chantal E.
Crystal structure of 1-(2,6-diiso­propyl­phen­yl)-1H-imidazole
title Crystal structure of 1-(2,6-diiso­propyl­phen­yl)-1H-imidazole
title_full Crystal structure of 1-(2,6-diiso­propyl­phen­yl)-1H-imidazole
title_fullStr Crystal structure of 1-(2,6-diiso­propyl­phen­yl)-1H-imidazole
title_full_unstemmed Crystal structure of 1-(2,6-diiso­propyl­phen­yl)-1H-imidazole
title_short Crystal structure of 1-(2,6-diiso­propyl­phen­yl)-1H-imidazole
title_sort crystal structure of 1-(2,6-diiso­propyl­phen­yl)-1h-imidazole
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10626946/
https://www.ncbi.nlm.nih.gov/pubmed/37936856
http://dx.doi.org/10.1107/S2056989023009179
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