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Crystal structure of di­benzyl­ammonium hydrogen (4-amino­phen­yl)arsonate monohydrate

The title salt, C(14)H(16)N(+)·C(6)H(7)AsNO(3) (−)·H(2)O or [(C(6)H(5)CH(2))(2)NH(2)][H(2)NC(6)H(4)As(OH)O(2)]·H(2)O, (I), was synthesized by mixing an aqueous solution of (4-amino­phenyl)­arsonic acid with an ethano­lic solution of di­benzyl­amine at room temperature. Compound I crystallizes in the...

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Detalles Bibliográficos
Autores principales: Traoré, Bocar, Diallo, Waly, Sidibé, Mamadou, Diop, Libasse, Plasseraud, Laurent, Cattey, Hélène
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10626960/
https://www.ncbi.nlm.nih.gov/pubmed/37936848
http://dx.doi.org/10.1107/S205698902300837X
Descripción
Sumario:The title salt, C(14)H(16)N(+)·C(6)H(7)AsNO(3) (−)·H(2)O or [(C(6)H(5)CH(2))(2)NH(2)][H(2)NC(6)H(4)As(OH)O(2)]·H(2)O, (I), was synthesized by mixing an aqueous solution of (4-amino­phenyl)­arsonic acid with an ethano­lic solution of di­benzyl­amine at room temperature. Compound I crystallizes in the monoclinic P2(1)/c space group. The three components forming I are linked via N—H⋯O and O—H⋯O inter­molecular hydrogen bonds, resulting in the propagation of an infinite zigzag chain. Additional weak inter­actions between neighbouring chains, such as π–π and N—H⋯O contacts, involving phenyl rings, –NH(2) and –As(OH)O(3) functions, and H(2)O, respectively, lead to a three-dimensional network.