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Crystal structure of dibenzylammonium hydrogen (4-aminophenyl)arsonate monohydrate
The title salt, C(14)H(16)N(+)·C(6)H(7)AsNO(3) (−)·H(2)O or [(C(6)H(5)CH(2))(2)NH(2)][H(2)NC(6)H(4)As(OH)O(2)]·H(2)O, (I), was synthesized by mixing an aqueous solution of (4-aminophenyl)arsonic acid with an ethanolic solution of dibenzylamine at room temperature. Compound I crystallizes in the...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10626960/ https://www.ncbi.nlm.nih.gov/pubmed/37936848 http://dx.doi.org/10.1107/S205698902300837X |
Sumario: | The title salt, C(14)H(16)N(+)·C(6)H(7)AsNO(3) (−)·H(2)O or [(C(6)H(5)CH(2))(2)NH(2)][H(2)NC(6)H(4)As(OH)O(2)]·H(2)O, (I), was synthesized by mixing an aqueous solution of (4-aminophenyl)arsonic acid with an ethanolic solution of dibenzylamine at room temperature. Compound I crystallizes in the monoclinic P2(1)/c space group. The three components forming I are linked via N—H⋯O and O—H⋯O intermolecular hydrogen bonds, resulting in the propagation of an infinite zigzag chain. Additional weak interactions between neighbouring chains, such as π–π and N—H⋯O contacts, involving phenyl rings, –NH(2) and –As(OH)O(3) functions, and H(2)O, respectively, lead to a three-dimensional network. |
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