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Crystal structure of dibenzylammonium hydrogen (4-aminophenyl)arsonate monohydrate
The title salt, C(14)H(16)N(+)·C(6)H(7)AsNO(3) (−)·H(2)O or [(C(6)H(5)CH(2))(2)NH(2)][H(2)NC(6)H(4)As(OH)O(2)]·H(2)O, (I), was synthesized by mixing an aqueous solution of (4-aminophenyl)arsonic acid with an ethanolic solution of dibenzylamine at room temperature. Compound I crystallizes in the...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10626960/ https://www.ncbi.nlm.nih.gov/pubmed/37936848 http://dx.doi.org/10.1107/S205698902300837X |
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author | Traoré, Bocar Diallo, Waly Sidibé, Mamadou Diop, Libasse Plasseraud, Laurent Cattey, Hélène |
author_facet | Traoré, Bocar Diallo, Waly Sidibé, Mamadou Diop, Libasse Plasseraud, Laurent Cattey, Hélène |
author_sort | Traoré, Bocar |
collection | PubMed |
description | The title salt, C(14)H(16)N(+)·C(6)H(7)AsNO(3) (−)·H(2)O or [(C(6)H(5)CH(2))(2)NH(2)][H(2)NC(6)H(4)As(OH)O(2)]·H(2)O, (I), was synthesized by mixing an aqueous solution of (4-aminophenyl)arsonic acid with an ethanolic solution of dibenzylamine at room temperature. Compound I crystallizes in the monoclinic P2(1)/c space group. The three components forming I are linked via N—H⋯O and O—H⋯O intermolecular hydrogen bonds, resulting in the propagation of an infinite zigzag chain. Additional weak interactions between neighbouring chains, such as π–π and N—H⋯O contacts, involving phenyl rings, –NH(2) and –As(OH)O(3) functions, and H(2)O, respectively, lead to a three-dimensional network. |
format | Online Article Text |
id | pubmed-10626960 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-106269602023-11-07 Crystal structure of dibenzylammonium hydrogen (4-aminophenyl)arsonate monohydrate Traoré, Bocar Diallo, Waly Sidibé, Mamadou Diop, Libasse Plasseraud, Laurent Cattey, Hélène Acta Crystallogr E Crystallogr Commun Research Communications The title salt, C(14)H(16)N(+)·C(6)H(7)AsNO(3) (−)·H(2)O or [(C(6)H(5)CH(2))(2)NH(2)][H(2)NC(6)H(4)As(OH)O(2)]·H(2)O, (I), was synthesized by mixing an aqueous solution of (4-aminophenyl)arsonic acid with an ethanolic solution of dibenzylamine at room temperature. Compound I crystallizes in the monoclinic P2(1)/c space group. The three components forming I are linked via N—H⋯O and O—H⋯O intermolecular hydrogen bonds, resulting in the propagation of an infinite zigzag chain. Additional weak interactions between neighbouring chains, such as π–π and N—H⋯O contacts, involving phenyl rings, –NH(2) and –As(OH)O(3) functions, and H(2)O, respectively, lead to a three-dimensional network. International Union of Crystallography 2023-10-05 /pmc/articles/PMC10626960/ /pubmed/37936848 http://dx.doi.org/10.1107/S205698902300837X Text en © Traoré et al. 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Traoré, Bocar Diallo, Waly Sidibé, Mamadou Diop, Libasse Plasseraud, Laurent Cattey, Hélène Crystal structure of dibenzylammonium hydrogen (4-aminophenyl)arsonate monohydrate |
title | Crystal structure of dibenzylammonium hydrogen (4-aminophenyl)arsonate monohydrate |
title_full | Crystal structure of dibenzylammonium hydrogen (4-aminophenyl)arsonate monohydrate |
title_fullStr | Crystal structure of dibenzylammonium hydrogen (4-aminophenyl)arsonate monohydrate |
title_full_unstemmed | Crystal structure of dibenzylammonium hydrogen (4-aminophenyl)arsonate monohydrate |
title_short | Crystal structure of dibenzylammonium hydrogen (4-aminophenyl)arsonate monohydrate |
title_sort | crystal structure of dibenzylammonium hydrogen (4-aminophenyl)arsonate monohydrate |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10626960/ https://www.ncbi.nlm.nih.gov/pubmed/37936848 http://dx.doi.org/10.1107/S205698902300837X |
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