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Crystal structure of di­benzyl­ammonium hydrogen (4-amino­phen­yl)arsonate monohydrate

The title salt, C(14)H(16)N(+)·C(6)H(7)AsNO(3) (−)·H(2)O or [(C(6)H(5)CH(2))(2)NH(2)][H(2)NC(6)H(4)As(OH)O(2)]·H(2)O, (I), was synthesized by mixing an aqueous solution of (4-amino­phenyl)­arsonic acid with an ethano­lic solution of di­benzyl­amine at room temperature. Compound I crystallizes in the...

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Autores principales: Traoré, Bocar, Diallo, Waly, Sidibé, Mamadou, Diop, Libasse, Plasseraud, Laurent, Cattey, Hélène
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10626960/
https://www.ncbi.nlm.nih.gov/pubmed/37936848
http://dx.doi.org/10.1107/S205698902300837X
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author Traoré, Bocar
Diallo, Waly
Sidibé, Mamadou
Diop, Libasse
Plasseraud, Laurent
Cattey, Hélène
author_facet Traoré, Bocar
Diallo, Waly
Sidibé, Mamadou
Diop, Libasse
Plasseraud, Laurent
Cattey, Hélène
author_sort Traoré, Bocar
collection PubMed
description The title salt, C(14)H(16)N(+)·C(6)H(7)AsNO(3) (−)·H(2)O or [(C(6)H(5)CH(2))(2)NH(2)][H(2)NC(6)H(4)As(OH)O(2)]·H(2)O, (I), was synthesized by mixing an aqueous solution of (4-amino­phenyl)­arsonic acid with an ethano­lic solution of di­benzyl­amine at room temperature. Compound I crystallizes in the monoclinic P2(1)/c space group. The three components forming I are linked via N—H⋯O and O—H⋯O inter­molecular hydrogen bonds, resulting in the propagation of an infinite zigzag chain. Additional weak inter­actions between neighbouring chains, such as π–π and N—H⋯O contacts, involving phenyl rings, –NH(2) and –As(OH)O(3) functions, and H(2)O, respectively, lead to a three-dimensional network.
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spelling pubmed-106269602023-11-07 Crystal structure of di­benzyl­ammonium hydrogen (4-amino­phen­yl)arsonate monohydrate Traoré, Bocar Diallo, Waly Sidibé, Mamadou Diop, Libasse Plasseraud, Laurent Cattey, Hélène Acta Crystallogr E Crystallogr Commun Research Communications The title salt, C(14)H(16)N(+)·C(6)H(7)AsNO(3) (−)·H(2)O or [(C(6)H(5)CH(2))(2)NH(2)][H(2)NC(6)H(4)As(OH)O(2)]·H(2)O, (I), was synthesized by mixing an aqueous solution of (4-amino­phenyl)­arsonic acid with an ethano­lic solution of di­benzyl­amine at room temperature. Compound I crystallizes in the monoclinic P2(1)/c space group. The three components forming I are linked via N—H⋯O and O—H⋯O inter­molecular hydrogen bonds, resulting in the propagation of an infinite zigzag chain. Additional weak inter­actions between neighbouring chains, such as π–π and N—H⋯O contacts, involving phenyl rings, –NH(2) and –As(OH)O(3) functions, and H(2)O, respectively, lead to a three-dimensional network. International Union of Crystallography 2023-10-05 /pmc/articles/PMC10626960/ /pubmed/37936848 http://dx.doi.org/10.1107/S205698902300837X Text en © Traoré et al. 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Traoré, Bocar
Diallo, Waly
Sidibé, Mamadou
Diop, Libasse
Plasseraud, Laurent
Cattey, Hélène
Crystal structure of di­benzyl­ammonium hydrogen (4-amino­phen­yl)arsonate monohydrate
title Crystal structure of di­benzyl­ammonium hydrogen (4-amino­phen­yl)arsonate monohydrate
title_full Crystal structure of di­benzyl­ammonium hydrogen (4-amino­phen­yl)arsonate monohydrate
title_fullStr Crystal structure of di­benzyl­ammonium hydrogen (4-amino­phen­yl)arsonate monohydrate
title_full_unstemmed Crystal structure of di­benzyl­ammonium hydrogen (4-amino­phen­yl)arsonate monohydrate
title_short Crystal structure of di­benzyl­ammonium hydrogen (4-amino­phen­yl)arsonate monohydrate
title_sort crystal structure of di­benzyl­ammonium hydrogen (4-amino­phen­yl)arsonate monohydrate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10626960/
https://www.ncbi.nlm.nih.gov/pubmed/37936848
http://dx.doi.org/10.1107/S205698902300837X
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